Electrochemical oxidation of aliphatic carboxylates: Kinetics, thermodynamics, and evidence for a shift from a concerted to a stepwise mechanism in the presence of water
The mechanism and the oxidation potential of the dissociative single electron transfer for tetra-n-butylammonium acetate has been investigated via conventional (cyclic voltammetry) and convolution voltammetry. The oxidation potential for tetra-n-butylammonium acetate was determined to be 0.60 ± 0.10...
Main Author: | |
---|---|
Other Authors: | |
Format: | Others |
Published: |
Virginia Tech
2018
|
Subjects: | |
Online Access: | http://hdl.handle.net/10919/82522 |