Chlorine-38 for chlorine substitution in geometric and diastereomeric compounds: mechanism and stereochemistry
In order to determine how solvents control the stereochemical course of the hot substitution reactions, the stereochemistry of the energetic ³⁸Cl for Cl was studied in diastereomeric 1,2-dichloro-1,2-difluoroethane and the geometric isomers of 1,2-dichlorohexa-fluorocyclobutane. In each system, the...
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| Format: | Others |
| Language: | en_US |
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Virginia Polytechnic Institute and State University
2016
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| Online Access: | http://hdl.handle.net/10919/64734 |