Stereoelectronic effects in brominations of cyclopropylarenes and 9-alkylanthracenes
The free radical bromination of several cyclopropylarenes has been studied. The abstraction of a cyclopropyl hydrogen by bromine atom, which to date has been an unrecognized process, is demonstrated in this study. Specifically, when a cyclopropyl group is attached to the 9-position of an anthracene,...
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Format: | Others |
Language: | en_US |
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Virginia Polytechnic Institute and State University
2015
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Online Access: | http://hdl.handle.net/10919/54185 |