Transition metal-catalyzed reductive C-C bond forming hydrogenation/transfer hydrogenation and applications in the total synthesis of (+)-roxaticin

Transition metal-catalyzed reductive C-C bond forming hydrogenation/transfer hydrogenation and applications in the total synthesis of (+)-roxaticin

By simply hydrogenating enones in the presence of aldehydes at ambient temperature and pressure, aldol adducts are generated under neutral conditions in the absence of any stoichiometric byproducts. Using cationic rhodium complexes modified by tri(2-furyl)phosphine, highly syn-diastereoselective red...

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Bibliographic Details
Main Author: Han, Soo Bong, 1975-
Format: Others
Language:English
Published: 2011
Subjects:
Hydrogenation
Transfer hydrogenation
Aldol
Allylation
Enones
Vinyl ketones
Online Access:http://hdl.handle.net/2152/ETD-UT-2010-12-2239

Internet

http://hdl.handle.net/2152/ETD-UT-2010-12-2239

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