Redox behavior of lanthanide and main group complexes supported by a "clamshell" 1,2-bis(imino)acenaphthene (BIAN) ligand

Redox behavior of lanthanide and main group complexes supported by a "clamshell" 1,2-bis(imino)acenaphthene (BIAN) ligand

The reactions of the "clamshell" 1,2-bis(imino)acenaphthene (BIAN) ligand with decamethyleuropocene, boron triiodide, phosphorus triiodide, and tellurium tetraiodide have been investigated. The "clamshell" ligand undergoes one-electron reduction with decamethyleuropocene while...

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Bibliographic Details
Main Author: Gehman, Lauren Michelle
Format: Others
Language:English
Published: 2010
Subjects:
Clamshell
Ligand
BIAN-supported boron monoiodide
Electron reduction
Online Access:http://hdl.handle.net/2152/ETD-UT-2010-08-1867
id ndltd-UTEXAS-oai-repositories.lib.utexas.edu-2152-ETD-UT-2010-08-1867
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spelling ndltd-UTEXAS-oai-repositories.lib.utexas.edu-2152-ETD-UT-2010-08-18672015-09-20T16:56:26ZRedox behavior of lanthanide and main group complexes supported by a "clamshell" 1,2-bis(imino)acenaphthene (BIAN) ligandGehman, Lauren MichelleClamshellLigandBIAN-supported boron monoiodideElectron reductionThe reactions of the "clamshell" 1,2-bis(imino)acenaphthene (BIAN) ligand with decamethyleuropocene, boron triiodide, phosphorus triiodide, and tellurium tetraiodide have been investigated. The "clamshell" ligand undergoes one-electron reduction with decamethyleuropocene while treatment of this ligand with boron triiodide generates a BIAN-supported boron monoiodide via two-electron reduction. The reaction of the "clamshell" ligand with phosphorus triiodide involves a two-electron reduction of the BIAN backbone while that with tellurium tetraiodide yields a TeI2 complex without intermolecular charge transfer.text2010-12-17T21:14:37Z2010-12-17T21:14:42Z2010-12-17T21:14:37Z2010-12-17T21:14:42Z2010-082010-12-17August 20102010-12-17T21:14:42Zthesisapplication/pdfhttp://hdl.handle.net/2152/ETD-UT-2010-08-1867eng
collection NDLTD
language English
format Others
sources NDLTD
topic Clamshell
Ligand
BIAN-supported boron monoiodide
Electron reduction
spellingShingle Clamshell
Ligand
BIAN-supported boron monoiodide
Electron reduction
Gehman, Lauren Michelle
Redox behavior of lanthanide and main group complexes supported by a "clamshell" 1,2-bis(imino)acenaphthene (BIAN) ligand
description The reactions of the "clamshell" 1,2-bis(imino)acenaphthene (BIAN) ligand with decamethyleuropocene, boron triiodide, phosphorus triiodide, and tellurium tetraiodide have been investigated. The "clamshell" ligand undergoes one-electron reduction with decamethyleuropocene while treatment of this ligand with boron triiodide generates a BIAN-supported boron monoiodide via two-electron reduction. The reaction of the "clamshell" ligand with phosphorus triiodide involves a two-electron reduction of the BIAN backbone while that with tellurium tetraiodide yields a TeI2 complex without intermolecular charge transfer. === text
author Gehman, Lauren Michelle
author_facet Gehman, Lauren Michelle
author_sort Gehman, Lauren Michelle
title Redox behavior of lanthanide and main group complexes supported by a "clamshell" 1,2-bis(imino)acenaphthene (BIAN) ligand
title_short Redox behavior of lanthanide and main group complexes supported by a "clamshell" 1,2-bis(imino)acenaphthene (BIAN) ligand
title_full Redox behavior of lanthanide and main group complexes supported by a "clamshell" 1,2-bis(imino)acenaphthene (BIAN) ligand
title_fullStr Redox behavior of lanthanide and main group complexes supported by a "clamshell" 1,2-bis(imino)acenaphthene (BIAN) ligand
title_full_unstemmed Redox behavior of lanthanide and main group complexes supported by a "clamshell" 1,2-bis(imino)acenaphthene (BIAN) ligand
title_sort redox behavior of lanthanide and main group complexes supported by a "clamshell" 1,2-bis(imino)acenaphthene (bian) ligand
publishDate 2010
url http://hdl.handle.net/2152/ETD-UT-2010-08-1867
work_keys_str_mv AT gehmanlaurenmichelle redoxbehavioroflanthanideandmaingroupcomplexessupportedbyaclamshell12bisiminoacenaphthenebianligand
_version_ 1716821207514349568

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