The Kinetics and Mechanism of the Reaction of Molybdenum(V) with Iodine, Oxygen and Nitrate

Molybdenum compounds present a series of baffling chemical puzzles. By no means are all of these yet even clearly defined and many may never be. This complexity results from the ability of molybdenum to form six different oxidation states, which can possess three different coordination numbers. Furt...

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Main Author:	Guymon, Ervin Park
Format:	Others
Published:	DigitalCommons@USU 1965
Subjects:	Kinetics Mechanism Molybdenum Iodine Oxygen Nitrate Chemistry
Online Access:	https://digitalcommons.usu.edu/etd/7271 https://digitalcommons.usu.edu/cgi/viewcontent.cgi?article=8360&context=etd

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spelling	ndltd-UTAHS-oai-digitalcommons.usu.edu-etd-83602019-10-13T05:53:45Z The Kinetics and Mechanism of the Reaction of Molybdenum(V) with Iodine, Oxygen and Nitrate Guymon, Ervin Park Molybdenum compounds present a series of baffling chemical puzzles. By no means are all of these yet even clearly defined and many may never be. This complexity results from the ability of molybdenum to form six different oxidation states, which can possess three different coordination numbers. Furthermore, molybdenum compounds readily disproportionate to yield mixed valence compounds; and finally, molybdate ions readily aggregate in solution to form a variety of polyions by polymerization-condensation reactions which are controlled by pH and the concentration of the system. Molybdenum' s complexity can best be summed up in the words of the late Edgar Smith who described molybdenum to his classes as “ambidextrous, bi-sexual and polygamous.” 1965-05-01T07:00:00Z text application/pdf https://digitalcommons.usu.edu/etd/7271 https://digitalcommons.usu.edu/cgi/viewcontent.cgi?article=8360&context=etd Copyright for this work is held by the author. Transmission or reproduction of materials protected by copyright beyond that allowed by fair use requires the written permission of the copyright owners. Works not in the public domain cannot be commercially exploited without permission of the copyright owner. Responsibility for any use rests exclusively with the user. For more information contact digitalcommons@usu.edu. All Graduate Theses and Dissertations DigitalCommons@USU Kinetics Mechanism Molybdenum Iodine Oxygen Nitrate Chemistry
collection	NDLTD
format	Others
sources	NDLTD
topic	Kinetics Mechanism Molybdenum Iodine Oxygen Nitrate Chemistry
spellingShingle	Kinetics Mechanism Molybdenum Iodine Oxygen Nitrate Chemistry Guymon, Ervin Park The Kinetics and Mechanism of the Reaction of Molybdenum(V) with Iodine, Oxygen and Nitrate
description	Molybdenum compounds present a series of baffling chemical puzzles. By no means are all of these yet even clearly defined and many may never be. This complexity results from the ability of molybdenum to form six different oxidation states, which can possess three different coordination numbers. Furthermore, molybdenum compounds readily disproportionate to yield mixed valence compounds; and finally, molybdate ions readily aggregate in solution to form a variety of polyions by polymerization-condensation reactions which are controlled by pH and the concentration of the system. Molybdenum' s complexity can best be summed up in the words of the late Edgar Smith who described molybdenum to his classes as “ambidextrous, bi-sexual and polygamous.”
author	Guymon, Ervin Park
author_facet	Guymon, Ervin Park
author_sort	Guymon, Ervin Park
title	The Kinetics and Mechanism of the Reaction of Molybdenum(V) with Iodine, Oxygen and Nitrate
title_short	The Kinetics and Mechanism of the Reaction of Molybdenum(V) with Iodine, Oxygen and Nitrate
title_full	The Kinetics and Mechanism of the Reaction of Molybdenum(V) with Iodine, Oxygen and Nitrate
title_fullStr	The Kinetics and Mechanism of the Reaction of Molybdenum(V) with Iodine, Oxygen and Nitrate
title_full_unstemmed	The Kinetics and Mechanism of the Reaction of Molybdenum(V) with Iodine, Oxygen and Nitrate
title_sort	kinetics and mechanism of the reaction of molybdenum(v) with iodine, oxygen and nitrate
publisher	DigitalCommons@USU
publishDate	1965
url	https://digitalcommons.usu.edu/etd/7271 https://digitalcommons.usu.edu/cgi/viewcontent.cgi?article=8360&context=etd
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The Kinetics and Mechanism of the Reaction of Molybdenum(V) with Iodine, Oxygen and Nitrate

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