Effect of Induction-Heat Post-Curing on Residual Stresses in Fast-Curing Carbon Fibre Reinforced Composites

• Main Author: Bettelli, Mercedes Amelia
• Format: Others
• Language: English
• Published: Luleå tekniska universitet, Institutionen för teknikvetenskap och matematik 2020
• Subjects: Carbon Fibres Reinforced Polymer Composite; epoxy resins; cure behaviour; residual stress and shape distortions; Materials Engineering; Materialteknik
• Online Access: http://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-80527

Manufacturing induced shape distortions is a common problem for composite materials. Due to the non-isotropic nature of carbon fibre reinforced polymers (CFRP) unavoidable deformations occur during part production. During fabrication of polymer composites, the material obtains its final shape at elevated temperatures. The curing process involves a transition from the liquid state to the solid, glassy state, allowing bonding between fibres and matrix. As the material cools the mismatch in thermal expansion coefficients and cure shrinkage obtained during the matrix polymerization leads to residual stresses on the mechanical level within composite part. There is a great interest from the aircraft and automotive industries, to increase the ability to understand development of shape distortions and residual stresses during the cure, since these deformations often lead to dissatisfaction of tolerances and it is essential to predict the deformations beforehand in order to compensate time and cost.  In this context, a study of residual stresses during the curing process of thermosetting resin composites is presented. A methodology is proposed for predicting the formation and development of manufacturing- induced residual stresses. The present project reports on a comprehensive experimental study on the dependency of different short curing cycles on the build-up of residual stresses in a carbon fibre/fast-curing epoxy system and evaluate of post-curing methods through induction heating and oven post-curing with unidirectional [904] and unsymmetrical [9020] laminates. It includes characterization in thermo-elastic properties and degree-of-cure of the material by Thermal bending test, thermal expansion test, mechanical tensile test and Differential Scanning Calorimetry (DSC) in non-post-cured and post-cured laminates. The results showed slight variation in the thermal properties and not effect in the mechanical properties at different cure and post-curing conditions. Analytical data by Laminate Analysis program validated the experimental thermo-elastic data with analytical simulations. In addition, it is shown improvements in the temperature distributions in the post-curing by induction heating with different experimental set-ups, however, oven post-curing showed a more systematic system, higher heat efficient a low cure temperature, with more consistent mechanisms of shape distortions and residual stresses compared to induction heating. These findings are relevant for the future development of prediction methods for process induced deformations of Fast Curing Epoxy Resins (FCER).