Methods for Asymmetric Olefination Reactions; Development and Application to Natural Product Synthesis

Methods for Asymmetric Olefination Reactions; Development and Application to Natural Product Synthesis

This thesis deals with the development and application of methods for asymmetric olefinations, in particular Horner-Wadsworth-Emmons (HWE) reactions, in the synthesis of certain natural products. Relying on asymmetric HWE reactions to access key building blocks, two natu-ral products, pyranicin and...

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Bibliographic Details
Main Author: Strand, Daniel
Format: Doctoral Thesis
Language:English
Published: KTH, Organisk kemi 2006
Subjects:
Antitumor agents
Asymmetric Horner-Wadsworth-Emmons
Desymmetrization
Metal-catalyzed olefination
Mucocin
Palladium-catalyzed allylic substitution
Parallel kinetic resolution
Pyranicin
Pyragonicin
Rhenium
Stereoconvergent synthesis
Stereodivergent synthesis
Stereoselective synthesis
Tetrahydropyran
Wittig reaction
Organic chemistry
Organisk kemi
Online Access:http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-4088
http://nbn-resolving.de/urn:isbn:91-7178-427-6

Internet

http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-4088
http://nbn-resolving.de/urn:isbn:91-7178-427-6

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