SOLVENT EFFECTS IN THE ANIONIC POLYMERIZATION OF ALPHA, ALPHA-DISUBSTITUTED -BETA- PROPIOLACTONES

SOLVENT EFFECTS IN THE ANIONIC POLYMERIZATION OF ALPHA, ALPHA-DISUBSTITUTED -BETA- PROPIOLACTONES

The effect of solvent polarity on the anionic polymerization rates of (alpha), (alpha)-disubstituted-(beta)-propiolactones was studied. Polymerization of (alpha)-methyl-(alpha)-propyl-(beta)-propiolactone in tetrahydrofuran was a living polymerization. In dimethyl sulfoxide, however, nucleophilic at...

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Bibliographic Details
Main Author:	MINTER, EILEEN MONE
Language:	ENG
Published:	ScholarWorks@UMass Amherst 1983
Subjects:	Polymers
Online Access:	https://scholarworks.umass.edu/dissertations/AAI8317484

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