Reactivity of molybdenum nitrosyl alkyl complexes
Hydrogenation of the bis(alkyl) complex, Cp*Mo(NO)(CH₂SiMe₃)₂,yields the bimetallic oxo bridging-nitrido complex, [Cp*Mo(NO)( CH₂SiMe₃)](μ- N)[Cp*Mo(O)(CH CH₂SiMe₃)].When the alkyl group of the bis(alkyl) precursor is changed to neopentyl (R CH₂CMe₂)or neophyl (R =CH₂CMe₂Ph),intermediate bridging...
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| Format: | Others |
| Language: | English |
| Published: |
2009
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| Online Access: | http://hdl.handle.net/2429/8696 |