o-Phenylene bridged diamidophosphine complexes of groups 4 and 5 metals for dinitrogen activation
A series of diamidophosphine donor sets (ipropNPN, tolNPN and phNPN) was prepared, whereby the arylamido groups have no ortho substituents. This allowed for the Buchwald-Hartwig arylamination to be replaced by a directed ortho metalation (DOM) process, sourcing commercial diarylamines. Amido and chl...
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| Language: | English |
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University of British Columbia
2014
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| Online Access: | http://hdl.handle.net/2429/51247 |