The synthesis and reactivity of tantalum diamidophosphine complexes featuring an activated alkyne unit
A series of tantalum complexes supported by the diamidophosphine ligand [PhNPN*] were synthesized using Ta(alkyne)Cl₃(DME), Ta(V) reagents that feature a reduced alkyne unit: [PhNPN*]Ta(3-hexyne)X, and [PhNPN*]Ta(BTA)X (X = Cl, H, alkyl, N₃; BTA = bis(trimethylsilyl)acetylene). For these complexes,...
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| Language: | English |
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University of British Columbia
2014
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| Online Access: | http://hdl.handle.net/2429/47058 |