Cavitation erosion of nickel aluminides

Cavitation erosion is a major problem encountered in hydraulic machinery components. Presently, solution to the problem is sought through a two-fold approach of machine design and application of cavitation resistant materials. Stainless steels are commonly used for cavitation protection. Cobalt b...

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Bibliographic Details
Main Author: Salvi, Raj P.
Format: Others
Language:English
Published: 2009
Online Access:http://hdl.handle.net/2429/4668
Description
Summary:Cavitation erosion is a major problem encountered in hydraulic machinery components. Presently, solution to the problem is sought through a two-fold approach of machine design and application of cavitation resistant materials. Stainless steels are commonly used for cavitation protection. Cobalt based alloys (stellites) and NiTi intermetallic compound are the best materials at present known to resist cavitation erosion. Physical and mechanical properties of various tested materials do not seem to correlate well with the cavitation erosion resistance of these materials. The present study was done to investigate the cavitation erosion resistance of the intermetallic nickel aluminides Ni₃Al and NiAl. An ultrasonic (20 KHz) vibratory test apparatus was used to conduct tests with a modification to the ASTM G-32-92 method. The cavitation intensity and the surface finish were varied, from the specification, to investigate their effects on the cavitation erosion resistance of NiAl. Scanning electron microscopy and X-ray diffraction methods were used as aids in analyzing the results. Unalloyed stoichiometric Ni₃Al was found to exhibit a higher cavitation erosion resistance that boron (0.2 wt. %) doped Ni₃Al. Alloying with boron imparts room temperature ductility to the otherwise brittle Ni₃Al compound. Investigations of deviation from stoichiometry were conducted on NiAl in the compositional range of 47 - 62.2 at. % Ni in this work. The erosion rate was found to decrease monotomically with increasing nickel content, in the range tested. Strain induced martensitic transformation was found to be associated with the compositions which showed the low cavitation erosion rates. Thermally induced martensite which was present in these compositions, was found to be detrimental to the cavitation erosion resistance of NiAl. NiAl compositions of 58 at. % Ni and 62.2 at. % Ni showed cavitation erosion resistance comparable to that of the best known intermetallic NiTi. However, in terms of materials processing NiAl offers advantages over NiTi. Hence NiAl could find a niche as an industrially important material for cavitation protection of hydraulic machinery. The most desirable NiAl compositions exhibit unusual but desirable variations of erosion rate with cavitation intensity. Further studies are needed for a better understanding of this phenomenon. === Applied Science, Faculty of === Materials Engineering, Department of === Graduate