The chemical characteristics of transition-metal organometallic nitrosyl complexes
The reactions of (n⁵-C₅H₅)Cr (CO)₂ (NO) with halogens result in either (n⁵-C₅H₅)Cr (CO)₂X (NO) (X=C1 or Br) or [(n⁵-C₅H₅)Cr (NO)I]₂. Further treatment of the iodo-complex with excess I₂ or NO leads to the formation of (n⁵-C₅H₅)Cr (NO)₂I. This complex also results from thermal decomposition of the di...
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| Language: | English |
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University of British Columbia
2010
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| Online Access: | http://hdl.handle.net/2429/25654 |