The design of organoiron and organic polymers containing azo dyes and calixarenes
Organic azo dye polymers are prepared from the ring-opening metathesis polymerization of azo dye functionalized norbornenes. These polymers are examined for their trans-cis¬ isomeration, UV-visible properties, and their acid sensing capabilities. The organoiron polymers are prepared through polycond...
Main Author: | |
---|---|
Language: | English |
Published: |
University of British Columbia
2010
|
Online Access: | http://hdl.handle.net/2429/18821 |
id |
ndltd-UBC-oai-circle.library.ubc.ca-2429-18821 |
---|---|
record_format |
oai_dc |
spelling |
ndltd-UBC-oai-circle.library.ubc.ca-2429-188212018-01-05T17:24:06Z The design of organoiron and organic polymers containing azo dyes and calixarenes Shipman, Patrick Oliver Organic azo dye polymers are prepared from the ring-opening metathesis polymerization of azo dye functionalized norbornenes. These polymers are examined for their trans-cis¬ isomeration, UV-visible properties, and their acid sensing capabilities. The organoiron polymers are prepared through polycondensation reactions between organoiron azo dye complexes and O-, S-, or N-containing dinucleophiles. These polymers are analyzed for their thermal and UV-visible properties. The synthesis and characterization of upper rim functionalized calix[4]arenes are described. Calix[4]arenes containing propanol groups on either the 5- or both the 5- and 11- positions were prepared. These calixarenes also contained either: phenolic, propoxy, or t-butyl-dimethyl-siloxy groups on the lower rim. These calixarenes were reacted with chloro-terminated organoiron carboxylic acid complexes to prepare metallocalix[4]arenes containing one, two, or four metal centres on their upper rims. The metallocalix[4]arenes were used to prepare calix[4]arene containing azo dyes, or ferrocenes. These metallocalix[4]arenes were also used to prepare organoiron based polycalixarenes. Organic polymers were also prepared from the organic upper rim propanol functionalized calix[4]arenes. The metallocalix[4]arenes were additionally studied for their electrochemical properties. The azo dye containing metallocalix[4]arenes were studied for their UV-visible properties and acid sensing capabilities. The polycalix[4]arenes were additionally studied through gel permeation chromatography, thermal gravimetric analysis and differential scanning calorimetry. Irving K. Barber School of Arts and Sciences (Okanagan) Chemistry, Department of (Okanagan) Graduate 2010-01-21T15:17:06Z 2010-01-21T15:17:06Z 2010 2010-05 Text Thesis/Dissertation http://hdl.handle.net/2429/18821 eng Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ University of British Columbia |
collection |
NDLTD |
language |
English |
sources |
NDLTD |
description |
Organic azo dye polymers are prepared from the ring-opening metathesis polymerization of azo dye functionalized norbornenes. These polymers are examined for their trans-cis¬ isomeration, UV-visible properties, and their acid sensing capabilities. The organoiron polymers are prepared through polycondensation reactions between organoiron azo dye complexes and O-, S-, or N-containing dinucleophiles. These polymers are analyzed for their thermal and UV-visible properties.
The synthesis and characterization of upper rim functionalized calix[4]arenes are described. Calix[4]arenes containing propanol groups on either the 5- or both the 5- and 11- positions were prepared. These calixarenes also contained either: phenolic, propoxy, or t-butyl-dimethyl-siloxy groups on the lower rim. These calixarenes were reacted with chloro-terminated organoiron carboxylic acid complexes to prepare metallocalix[4]arenes containing one, two, or four metal centres on their upper rims. The metallocalix[4]arenes were used to prepare calix[4]arene containing azo dyes, or ferrocenes. These metallocalix[4]arenes were also used to prepare organoiron based polycalixarenes. Organic polymers were also prepared from the organic upper rim propanol functionalized calix[4]arenes. The metallocalix[4]arenes were additionally studied for their electrochemical properties. The azo dye containing metallocalix[4]arenes were studied for their UV-visible properties and acid sensing capabilities. The polycalix[4]arenes were additionally studied through gel permeation chromatography, thermal gravimetric analysis and differential scanning calorimetry. === Irving K. Barber School of Arts and Sciences (Okanagan) === Chemistry, Department of (Okanagan) === Graduate |
author |
Shipman, Patrick Oliver |
spellingShingle |
Shipman, Patrick Oliver The design of organoiron and organic polymers containing azo dyes and calixarenes |
author_facet |
Shipman, Patrick Oliver |
author_sort |
Shipman, Patrick Oliver |
title |
The design of organoiron and organic polymers containing azo dyes and calixarenes |
title_short |
The design of organoiron and organic polymers containing azo dyes and calixarenes |
title_full |
The design of organoiron and organic polymers containing azo dyes and calixarenes |
title_fullStr |
The design of organoiron and organic polymers containing azo dyes and calixarenes |
title_full_unstemmed |
The design of organoiron and organic polymers containing azo dyes and calixarenes |
title_sort |
design of organoiron and organic polymers containing azo dyes and calixarenes |
publisher |
University of British Columbia |
publishDate |
2010 |
url |
http://hdl.handle.net/2429/18821 |
work_keys_str_mv |
AT shipmanpatrickoliver thedesignoforganoironandorganicpolymerscontainingazodyesandcalixarenes AT shipmanpatrickoliver designoforganoironandorganicpolymerscontainingazodyesandcalixarenes |
_version_ |
1718582328989581312 |