Negative ion photoelectron spectroscopy of cobalt tricarbonylnitrosyl

Negative ion photoelectron spectroscopy of cobalt tricarbonylnitrosyl

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Photoelectron spectra are reported for the Co(CO)₃NO⁻ and Co(CO)₂NO⁻ anions produced from cobalt tricarbonylnitrosyl in a pulsed valve source. The 355 nm spectra were obtained at a calculated electronic kinetic energy resolution of 96 meV using a newly constructed fixed-frequency negative ion photoe...

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Main Author: Turner, Nicholas James
Format: Others
Language:English
Published: 2008
Online Access:http://hdl.handle.net/2429/1512
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spelling ndltd-UBC-oai-circle.library.ubc.ca-2429-15122018-01-05T17:30:37Z Negative ion photoelectron spectroscopy of cobalt tricarbonylnitrosyl Turner, Nicholas James Photoelectron spectra are reported for the Co(CO)₃NO⁻ and Co(CO)₂NO⁻ anions produced from cobalt tricarbonylnitrosyl in a pulsed valve source. The 355 nm spectra were obtained at a calculated electronic kinetic energy resolution of 96 meV using a newly constructed fixed-frequency negative ion photoelectron spectrometer, which is described. Electron affinities of 1.72 (±0.03) eV for Co(CO)₃NO and 1.73 (±0.03) eV for Co(CO)₂NO are obtained. The photoelectron spectrum for Co(CO)₃NO⁻ is consistent with a geometry change from a linear Co-N-O group in the neutral molecule to a bent configuration in the corresponding negative ion. Science, Faculty of Chemistry, Department of Graduate 2008-08-26T22:28:03Z 2008-08-26T22:28:03Z 1993 1993-11 Text Thesis/Dissertation http://hdl.handle.net/2429/1512 eng For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use. 2593338 bytes application/pdf
collection NDLTD
language English
format Others
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description Photoelectron spectra are reported for the Co(CO)₃NO⁻ and Co(CO)₂NO⁻ anions produced from cobalt tricarbonylnitrosyl in a pulsed valve source. The 355 nm spectra were obtained at a calculated electronic kinetic energy resolution of 96 meV using a newly constructed fixed-frequency negative ion photoelectron spectrometer, which is described. Electron affinities of 1.72 (±0.03) eV for Co(CO)₃NO and 1.73 (±0.03) eV for Co(CO)₂NO are obtained. The photoelectron spectrum for Co(CO)₃NO⁻ is consistent with a geometry change from a linear Co-N-O group in the neutral molecule to a bent configuration in the corresponding negative ion. === Science, Faculty of === Chemistry, Department of === Graduate
author Turner, Nicholas James
spellingShingle Turner, Nicholas James
Negative ion photoelectron spectroscopy of cobalt tricarbonylnitrosyl
author_facet Turner, Nicholas James
author_sort Turner, Nicholas James
title Negative ion photoelectron spectroscopy of cobalt tricarbonylnitrosyl
title_short Negative ion photoelectron spectroscopy of cobalt tricarbonylnitrosyl
title_full Negative ion photoelectron spectroscopy of cobalt tricarbonylnitrosyl
title_fullStr Negative ion photoelectron spectroscopy of cobalt tricarbonylnitrosyl
title_full_unstemmed Negative ion photoelectron spectroscopy of cobalt tricarbonylnitrosyl
title_sort negative ion photoelectron spectroscopy of cobalt tricarbonylnitrosyl
publishDate 2008
url http://hdl.handle.net/2429/1512
work_keys_str_mv AT turnernicholasjames negativeionphotoelectronspectroscopyofcobalttricarbonylnitrosyl
_version_ 1718586102733864960

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