The sintering behavior and diffusion mechanism analysis of nano–size ceria based electrolytes

碩士 === 國立臺北科技大學 === 材料科學與工程研究所 === 107 === In this study, Ce0.8Sm0.2O1.9 (SDC20), Ce0.8Sm0.15Ca0.025Sr0.025O1.875 (SSCDC) and Ce0.6La0.4O1.8 (LDC20) were synthesized by a sol–gel method. The calcined powders were followed by XRD, Lazer light scattering particle analyzer and TEM. The result showed th...

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Bibliographic Details
Main Authors: Ching-Yuan Lin, 林敬原
Other Authors: Yu–Chuan Wu
Format: Others
Language:zh-TW
Published: 2018
Online Access:http://ndltd.ncl.edu.tw/handle/h92rwe
Description
Summary:碩士 === 國立臺北科技大學 === 材料科學與工程研究所 === 107 === In this study, Ce0.8Sm0.2O1.9 (SDC20), Ce0.8Sm0.15Ca0.025Sr0.025O1.875 (SSCDC) and Ce0.6La0.4O1.8 (LDC20) were synthesized by a sol–gel method. The calcined powders were followed by XRD, Lazer light scattering particle analyzer and TEM. The result showed that fluorite–type ceria–based solid solutions. The particle size were fluorite–type ceria–based solid solutions; the particle sizes were 0.685, 1.03 and 0.822μm, respectively; the grain size were 46, 56, and 35 nm. The sintering conditions were divide by isothermal and non-isothermal. The sintering behaviour of ceria powder was investigated.It showed SSCDC has highest densification, and the diensification activation energy was 436 kJ/mol