Structural stabilization effects of SiNx/Si thin film anodes for lithium ion batteries

碩士 === 逢甲大學 === 材料科學與工程學系 === 107 === In this report, we study the electrochemical performance of amorphous silicon as the anode for lithium ion batteries. Silicon has high theatrical capacity of 4200 mAh/g toward lithium metal. However, Li insertion/Li extraction of silicon electrode causes huge vo...

Full description

Bibliographic Details
Main Authors: CHENG, KA-CHUN, 鄭嘉俊
Other Authors: CHIU, KUO-FENG
Format: Others
Language:zh-TW
Published: 2019
Online Access:http://ndltd.ncl.edu.tw/handle/2g69g9
id ndltd-TW-107FCU00159018
record_format oai_dc
spelling ndltd-TW-107FCU001590182019-08-23T03:46:06Z http://ndltd.ncl.edu.tw/handle/2g69g9 Structural stabilization effects of SiNx/Si thin film anodes for lithium ion batteries 具結構穩定效應之氮化矽/矽薄膜負極 CHENG, KA-CHUN 鄭嘉俊 碩士 逢甲大學 材料科學與工程學系 107 In this report, we study the electrochemical performance of amorphous silicon as the anode for lithium ion batteries. Silicon has high theatrical capacity of 4200 mAh/g toward lithium metal. However, Li insertion/Li extraction of silicon electrode causes huge volume expansion. In this study, radio frequency (RF) magnetron sputtering is used to deposit amorphous silicon thin films on nickel foam current collectors. This flexible three-dimensional structure is found to relieve stress caused by the volume expansion. Furthermore, we sputter a SiNx thin film on silicon to be a buffer layer. From the potential window of 1.2 V - 0.01 V, long cycle test have been executed to investigate the electrochemical performances of various N-Si coated Si-based lithium ion batteries anode materials. The cycling stability is enhanced via nitride layer coating as silicon nitride films are converted to Li3N with covered Si thin films. After 300th cycle, the capacity retention is 96% and the discharge capacity is 1380 mAh/g due to low charge transfer resistance resulted from silicon nitride films. The results reveal that the inactive phase could be a good buffer layer for Si anodes. CHIU, KUO-FENG 邱國峰 2019 學位論文 ; thesis 79 zh-TW
collection NDLTD
language zh-TW
format Others
sources NDLTD
description 碩士 === 逢甲大學 === 材料科學與工程學系 === 107 === In this report, we study the electrochemical performance of amorphous silicon as the anode for lithium ion batteries. Silicon has high theatrical capacity of 4200 mAh/g toward lithium metal. However, Li insertion/Li extraction of silicon electrode causes huge volume expansion. In this study, radio frequency (RF) magnetron sputtering is used to deposit amorphous silicon thin films on nickel foam current collectors. This flexible three-dimensional structure is found to relieve stress caused by the volume expansion. Furthermore, we sputter a SiNx thin film on silicon to be a buffer layer. From the potential window of 1.2 V - 0.01 V, long cycle test have been executed to investigate the electrochemical performances of various N-Si coated Si-based lithium ion batteries anode materials. The cycling stability is enhanced via nitride layer coating as silicon nitride films are converted to Li3N with covered Si thin films. After 300th cycle, the capacity retention is 96% and the discharge capacity is 1380 mAh/g due to low charge transfer resistance resulted from silicon nitride films. The results reveal that the inactive phase could be a good buffer layer for Si anodes.
author2 CHIU, KUO-FENG
author_facet CHIU, KUO-FENG
CHENG, KA-CHUN
鄭嘉俊
author CHENG, KA-CHUN
鄭嘉俊
spellingShingle CHENG, KA-CHUN
鄭嘉俊
Structural stabilization effects of SiNx/Si thin film anodes for lithium ion batteries
author_sort CHENG, KA-CHUN
title Structural stabilization effects of SiNx/Si thin film anodes for lithium ion batteries
title_short Structural stabilization effects of SiNx/Si thin film anodes for lithium ion batteries
title_full Structural stabilization effects of SiNx/Si thin film anodes for lithium ion batteries
title_fullStr Structural stabilization effects of SiNx/Si thin film anodes for lithium ion batteries
title_full_unstemmed Structural stabilization effects of SiNx/Si thin film anodes for lithium ion batteries
title_sort structural stabilization effects of sinx/si thin film anodes for lithium ion batteries
publishDate 2019
url http://ndltd.ncl.edu.tw/handle/2g69g9
work_keys_str_mv AT chengkachun structuralstabilizationeffectsofsinxsithinfilmanodesforlithiumionbatteries
AT zhèngjiājùn structuralstabilizationeffectsofsinxsithinfilmanodesforlithiumionbatteries
AT chengkachun jùjiégòuwěndìngxiàoyīngzhīdànhuàxìxìbáomófùjí
AT zhèngjiājùn jùjiégòuwěndìngxiàoyīngzhīdànhuàxìxìbáomófùjí
_version_ 1719236369956470784