2,2'' and 3,3'' Substituted Thienoisoindigo-Based Small Molecules for the Applications of Organic Photovoltaics

碩士 === 淡江大學 === 化學學系碩士班 === 106 ===   In this research, we synthesized a series of thienoisoindigo (TII)-based small molecules (H1-H7) and applied them to develop organic photovoltaics (OPVs). The TII-based small molecules use carbazole (H1), N-phenylcarbazole (H2, H4, H7), and 1,3-di(9H-carbazol-9-...

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Main Authors: Yu-Ting Hsu, 徐郁婷
Other Authors: Chih-Hsin Chen
Format: Others
Language:zh-TW
Published: 2018
Online Access:http://ndltd.ncl.edu.tw/handle/qpq589
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spelling ndltd-TW-106TKU050650132019-05-16T01:32:16Z http://ndltd.ncl.edu.tw/handle/qpq589 2,2'' and 3,3'' Substituted Thienoisoindigo-Based Small Molecules for the Applications of Organic Photovoltaics 2,2''和3,3''取代以噻吩並異靛藍為主體的小分子在有機光伏打電池上之應用 Yu-Ting Hsu 徐郁婷 碩士 淡江大學 化學學系碩士班 106   In this research, we synthesized a series of thienoisoindigo (TII)-based small molecules (H1-H7) and applied them to develop organic photovoltaics (OPVs). The TII-based small molecules use carbazole (H1), N-phenylcarbazole (H2, H4, H7), and 1,3-di(9H-carbazol-9-yl) benzene (H3), triphenylamine (H5, H7), benzene (H6) as electron donor (D), while TII as electron acceptor (A). Such D-A-D structure allowed the molecule to exhibit a strong intramolecular charge transfer such that they can absorb the light from visible and partially near-infrared (NIR) region. The bulk heterojunction (BHJ) solar cell device fabricated by using H2/PC61BM as the active layer exhibited a power conversion efficiency (PCE) of 0.82%, showing the potential of TII-based dyes for NIR organic photovoltaics (OPVs). Chih-Hsin Chen 陳志欣 2018 學位論文 ; thesis 128 zh-TW
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language zh-TW
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sources NDLTD
description 碩士 === 淡江大學 === 化學學系碩士班 === 106 ===   In this research, we synthesized a series of thienoisoindigo (TII)-based small molecules (H1-H7) and applied them to develop organic photovoltaics (OPVs). The TII-based small molecules use carbazole (H1), N-phenylcarbazole (H2, H4, H7), and 1,3-di(9H-carbazol-9-yl) benzene (H3), triphenylamine (H5, H7), benzene (H6) as electron donor (D), while TII as electron acceptor (A). Such D-A-D structure allowed the molecule to exhibit a strong intramolecular charge transfer such that they can absorb the light from visible and partially near-infrared (NIR) region. The bulk heterojunction (BHJ) solar cell device fabricated by using H2/PC61BM as the active layer exhibited a power conversion efficiency (PCE) of 0.82%, showing the potential of TII-based dyes for NIR organic photovoltaics (OPVs).
author2 Chih-Hsin Chen
author_facet Chih-Hsin Chen
Yu-Ting Hsu
徐郁婷
author Yu-Ting Hsu
徐郁婷
spellingShingle Yu-Ting Hsu
徐郁婷
2,2'' and 3,3'' Substituted Thienoisoindigo-Based Small Molecules for the Applications of Organic Photovoltaics
author_sort Yu-Ting Hsu
title 2,2'' and 3,3'' Substituted Thienoisoindigo-Based Small Molecules for the Applications of Organic Photovoltaics
title_short 2,2'' and 3,3'' Substituted Thienoisoindigo-Based Small Molecules for the Applications of Organic Photovoltaics
title_full 2,2'' and 3,3'' Substituted Thienoisoindigo-Based Small Molecules for the Applications of Organic Photovoltaics
title_fullStr 2,2'' and 3,3'' Substituted Thienoisoindigo-Based Small Molecules for the Applications of Organic Photovoltaics
title_full_unstemmed 2,2'' and 3,3'' Substituted Thienoisoindigo-Based Small Molecules for the Applications of Organic Photovoltaics
title_sort 2,2'' and 3,3'' substituted thienoisoindigo-based small molecules for the applications of organic photovoltaics
publishDate 2018
url http://ndltd.ncl.edu.tw/handle/qpq589
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