Direct β-acylation of α,β-unsaturated Carbonyl Derivatives with Acyl chloride by Organophosphane

碩士 === 國立臺灣師範大學 === 化學系 === 106 === Part I: We have developed direct β-acylation of α,β-unsaturated 1,3-diketones derivative by organophosphane under mild conditions. The single isomeric product could be afforded. Remarkably, selective formation of β-acylation products or furans could be controlled...

Full description

Bibliographic Details
Main Authors:	Ku, Kuan-Chun, 古貫君
Other Authors:	Lin, Wen-Wei
Format:	Others
Language:	zh-TW
Online Access:	http://ndltd.ncl.edu.tw/handle/npc7uc

id	ndltd-TW-106NTNU5065013
record_format	oai_dc
spelling	ndltd-TW-106NTNU50650132019-05-16T00:52:21Z http://ndltd.ncl.edu.tw/handle/npc7uc Direct β-acylation of α,β-unsaturated Carbonyl Derivatives with Acyl chloride by Organophosphane 利用有機膦試劑誘導α,β-不飽合羰基衍生物進行β位醯化反應 Ku, Kuan-Chun 古貫君碩士國立臺灣師範大學化學系 106 Part I: We have developed direct β-acylation of α,β-unsaturated 1,3-diketones derivative by organophosphane under mild conditions. The single isomeric product could be afforded. Remarkably, selective formation of β-acylation products or furans could be controlled under the designed reaction condition. Part II: We have developed a organophosphane-mediated reaction for the synthesis of furanones from cinnamic acid derivatives in moderate to good yields under mild conditions. We wish to study this chemistry further, explore the reaction mechanism, and develop a standard protocol for the synthesis of a variety of α,β-unsaturated lactones. Lin, Wen-Wei 林文偉學位論文 ; thesis 50 zh-TW
collection	NDLTD
language	zh-TW
format	Others
sources	NDLTD
description	碩士 === 國立臺灣師範大學 === 化學系 === 106 === Part I: We have developed direct β-acylation of α,β-unsaturated 1,3-diketones derivative by organophosphane under mild conditions. The single isomeric product could be afforded. Remarkably, selective formation of β-acylation products or furans could be controlled under the designed reaction condition. Part II: We have developed a organophosphane-mediated reaction for the synthesis of furanones from cinnamic acid derivatives in moderate to good yields under mild conditions. We wish to study this chemistry further, explore the reaction mechanism, and develop a standard protocol for the synthesis of a variety of α,β-unsaturated lactones.
author2	Lin, Wen-Wei
author_facet	Lin, Wen-Wei Ku, Kuan-Chun 古貫君
author	Ku, Kuan-Chun 古貫君
spellingShingle	Ku, Kuan-Chun 古貫君 Direct β-acylation of α,β-unsaturated Carbonyl Derivatives with Acyl chloride by Organophosphane
author_sort	Ku, Kuan-Chun
title	Direct β-acylation of α,β-unsaturated Carbonyl Derivatives with Acyl chloride by Organophosphane
title_short	Direct β-acylation of α,β-unsaturated Carbonyl Derivatives with Acyl chloride by Organophosphane
title_full	Direct β-acylation of α,β-unsaturated Carbonyl Derivatives with Acyl chloride by Organophosphane
title_fullStr	Direct β-acylation of α,β-unsaturated Carbonyl Derivatives with Acyl chloride by Organophosphane
title_full_unstemmed	Direct β-acylation of α,β-unsaturated Carbonyl Derivatives with Acyl chloride by Organophosphane
title_sort	direct β-acylation of α,β-unsaturated carbonyl derivatives with acyl chloride by organophosphane
url	http://ndltd.ncl.edu.tw/handle/npc7uc
work_keys_str_mv	AT kukuanchun directbacylationofabunsaturatedcarbonylderivativeswithacylchloridebyorganophosphane AT gǔguànjūn directbacylationofabunsaturatedcarbonylderivativeswithacylchloridebyorganophosphane AT kukuanchun lìyòngyǒujīlìnshìjìyòudǎoabbùbǎohétāngjīyǎnshēngwùjìnxíngbwèixīhuàfǎnyīng AT gǔguànjūn lìyòngyǒujīlìnshìjìyòudǎoabbùbǎohétāngjīyǎnshēngwùjìnxíngbwèixīhuàfǎnyīng
_version_	1719170848540065792

Direct β-acylation of α,β-unsaturated Carbonyl Derivatives with Acyl chloride by Organophosphane

Similar Items