Studies on Macromolecule Containing Metalloporphyrin by Spectral and Electrochemical Methods
碩士 === 國立暨南國際大學 === 應用化學系 === 106 === In this study, we used a MPTA bridged unit and free based porphyrin to construct a macrocyclic structure by using Suzuki coupling method. The macrocyclic porphyrin and 4,4-Dipyridyl can form complexes by bonding. By using UV-Vis spectrometry, the spectral change...
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| Format: | Others |
| Language: | zh-TW |
| Published: |
2018
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| Online Access: | http://ndltd.ncl.edu.tw/handle/3k2zzk |
| Summary: | 碩士 === 國立暨南國際大學 === 應用化學系 === 106 === In this study, we used a MPTA bridged unit and free based porphyrin to construct a macrocyclic structure by using Suzuki coupling method. The macrocyclic porphyrin and 4,4-Dipyridyl can form complexes by bonding. By using UV-Vis spectrometry, the spectral changes of the complexes can be observed and the formation constant also calculated.
The redox potentials of macrocyclic porphyrin by using cyclic voltammetry. And the axis coordination group is added to the metal macrocyclic porphyrin. To observe the selectivity and potential change of the ligand by the large ring porphyrin, and then use the distance of the center to make the choice of the ligand.
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