Reaction, magnetic properties , spectroscopies and crystal structures of Hg(2-NCH3NCTPPH)Cl、Co(2-NCH3-21-CNNCTPP)(NCS)、Co(2-NCH3-21-CH2C6H5NCTPP)Cl
碩士 === 國立中興大學 === 化學系所 === 106 === We use Methyl iodide as 2-N substituted alkylation reagent to react with N-confused porphyrin to get 2-NCH3NCTPPH (2). After 2-N substituted alkylation, using HgCl2, CoCl2 ∙ 6H2O and Co(SCN)2 to react seperately with 2-NCH3NCTPPH (2) to get three NCP metal complexe...
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| Format: | Others |
| Language: | zh-TW |
| Published: |
2018
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| Online Access: | http://ndltd.ncl.edu.tw/handle/s93r38 |
| Summary: | 碩士 === 國立中興大學 === 化學系所 === 106 === We use Methyl iodide as 2-N substituted alkylation reagent to react with N-confused porphyrin to get 2-NCH3NCTPPH (2).
After 2-N substituted alkylation, using HgCl2, CoCl2 ∙ 6H2O and Co(SCN)2 to react seperately with 2-NCH3NCTPPH (2) to get three NCP metal complexes, diamagnetic of Hg(2-NCH3 -NCTPPH)Cl (3)、paramagnetic of Co(2-NCH3-21-CNNCTPP)(NCS) (4) and Co(2-NCH3-21-CH2C6H5NCTPP)Cl (5).
Then we use X-ray Single-Crystal Diffractometer, NMR spectroscopy and, etc., to determine the crystal structures and analyze their physical properties.
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