Hemicarceplex Formation Allows Ready Identification of the Isomers of the Metallofullerene Sc3N@C80 Using 1H and 13C NMR Spectroscopy

Hemicarceplex Formation Allows Ready Identification of the Isomers of the Metallofullerene Sc3N@C80 Using 1H and 13C NMR Spectroscopy

博士 === 國立臺灣大學 === 化學研究所 === 105 === A cyclotriveratrylene-based molecular cage forms hemicarceplexes that significantly increase the solubility of commercially available Sc3N@C80 in CDCl3. When incarcerated within the molecular cage, the two structural isomers of this metallofullerene, Sc3N@D5h-C80...

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Main Authors: Min-Yen Ku, 古旻諺
Other Authors: Sheng-Hsien Chiu
Format: Others
Language:zh-TW
Published: 2017
Online Access:http://ndltd.ncl.edu.tw/handle/84045054381687127612
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spelling ndltd-TW-105NTU050650902017-10-07T04:39:43Z http://ndltd.ncl.edu.tw/handle/84045054381687127612 Hemicarceplex Formation Allows Ready Identification of the Isomers of the Metallofullerene Sc3N@C80 Using 1H and 13C NMR Spectroscopy 利用 NMR 光譜鑑定準囚籠錯合物中的金屬富勒烯之結構異構物 Min-Yen Ku 古旻諺 博士 國立臺灣大學 化學研究所 105 A cyclotriveratrylene-based molecular cage forms hemicarceplexes that significantly increase the solubility of commercially available Sc3N@C80 in CDCl3. When incarcerated within the molecular cage, the two structural isomers of this metallofullerene, Sc3N@D5h-C80 and Sc3N@Ih-C80, displayed characteristic signals in both 1H and 13C NMR spectra, allowing direct identification of each isomer without the need to enrich the sample with 13C atoms. Sheng-Hsien Chiu 邱勝賢 2017 學位論文 ; thesis 93 zh-TW
collection NDLTD
language zh-TW
format Others
sources NDLTD
description 博士 === 國立臺灣大學 === 化學研究所 === 105 === A cyclotriveratrylene-based molecular cage forms hemicarceplexes that significantly increase the solubility of commercially available Sc3N@C80 in CDCl3. When incarcerated within the molecular cage, the two structural isomers of this metallofullerene, Sc3N@D5h-C80 and Sc3N@Ih-C80, displayed characteristic signals in both 1H and 13C NMR spectra, allowing direct identification of each isomer without the need to enrich the sample with 13C atoms.
author2 Sheng-Hsien Chiu
author_facet Sheng-Hsien Chiu
Min-Yen Ku
古旻諺
author Min-Yen Ku
古旻諺
spellingShingle Min-Yen Ku
古旻諺
Hemicarceplex Formation Allows Ready Identification of the Isomers of the Metallofullerene Sc3N@C80 Using 1H and 13C NMR Spectroscopy
author_sort Min-Yen Ku
title Hemicarceplex Formation Allows Ready Identification of the Isomers of the Metallofullerene Sc3N@C80 Using 1H and 13C NMR Spectroscopy
title_short Hemicarceplex Formation Allows Ready Identification of the Isomers of the Metallofullerene Sc3N@C80 Using 1H and 13C NMR Spectroscopy
title_full Hemicarceplex Formation Allows Ready Identification of the Isomers of the Metallofullerene Sc3N@C80 Using 1H and 13C NMR Spectroscopy
title_fullStr Hemicarceplex Formation Allows Ready Identification of the Isomers of the Metallofullerene Sc3N@C80 Using 1H and 13C NMR Spectroscopy
title_full_unstemmed Hemicarceplex Formation Allows Ready Identification of the Isomers of the Metallofullerene Sc3N@C80 Using 1H and 13C NMR Spectroscopy
title_sort hemicarceplex formation allows ready identification of the isomers of the metallofullerene sc3n@c80 using 1h and 13c nmr spectroscopy
publishDate 2017
url http://ndltd.ncl.edu.tw/handle/84045054381687127612
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