Lewis acid Catalyzed Reaction of 3-En-1-Ynamides with Nitrosoarene and Efficient Synthesis of 4-aminopyrimidine cores from Ynamides and Nitriles with OLED Applications

碩士 === 國立清華大學 === 化學系所 === 105 === Chapter 1 : The first chapter describes the zinc-catalyzed or tin-catalyzed reaction with diverse ynamides and nitrosoarenes through aza-Nazarov cyclization, allowing the facile and efficient synthesis of various 2-aminopyrroles in moderate to good yields. This pyr...

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Main Authors:	Huang, Wei-Ching, 黃韋靜
Other Authors:	Liu, Rai-Shung
Format:	Others
Language:	zh-TW
Published:	2017
Online Access:	http://ndltd.ncl.edu.tw/handle/753tfy

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spelling	ndltd-TW-105NTHU50650472019-05-15T23:53:46Z http://ndltd.ncl.edu.tw/handle/753tfy Lewis acid Catalyzed Reaction of 3-En-1-Ynamides with Nitrosoarene and Efficient Synthesis of 4-aminopyrimidine cores from Ynamides and Nitriles with OLED Applications 路易士酸催化炔醯胺與亞硝基苯進行環化反應以及炔醯胺與苯腈合成4-氨基嘧啶核心衍生物與其OLED應用 Huang, Wei-Ching 黃韋靜碩士國立清華大學化學系所 105 Chapter 1 : The first chapter describes the zinc-catalyzed or tin-catalyzed reaction with diverse ynamides and nitrosoarenes through aza-Nazarov cyclization, allowing the facile and efficient synthesis of various 2-aminopyrroles in moderate to good yields. This pyrrole fragment can be the precursor of several nature molecules. Chapter 2 : The second chapter describes concise TfOH-mediated [2 + 2 + 2] cycloaddition of ynamides with two discrete nitriles to synthesize seven pyrimidine-based emitters following by measurements of optical properties. These new derivatives show near-UV and blue fluorescent emissions (336 ~ 457 nm) with moderate quantum yields. One emitter (II-4g) was given an outstanding PL quantum yields (ηPL = 79%) with NUV emission which can be adjust and apply in UV-light OLED devices. Liu, Rai-Shung 劉瑞雄 2017 學位論文 ; thesis 160 zh-TW
collection	NDLTD
language	zh-TW
format	Others
sources	NDLTD
description	碩士 === 國立清華大學 === 化學系所 === 105 === Chapter 1 : The first chapter describes the zinc-catalyzed or tin-catalyzed reaction with diverse ynamides and nitrosoarenes through aza-Nazarov cyclization, allowing the facile and efficient synthesis of various 2-aminopyrroles in moderate to good yields. This pyrrole fragment can be the precursor of several nature molecules. Chapter 2 : The second chapter describes concise TfOH-mediated [2 + 2 + 2] cycloaddition of ynamides with two discrete nitriles to synthesize seven pyrimidine-based emitters following by measurements of optical properties. These new derivatives show near-UV and blue fluorescent emissions (336 ~ 457 nm) with moderate quantum yields. One emitter (II-4g) was given an outstanding PL quantum yields (ηPL = 79%) with NUV emission which can be adjust and apply in UV-light OLED devices.
author2	Liu, Rai-Shung
author_facet	Liu, Rai-Shung Huang, Wei-Ching 黃韋靜
author	Huang, Wei-Ching 黃韋靜
spellingShingle	Huang, Wei-Ching 黃韋靜 Lewis acid Catalyzed Reaction of 3-En-1-Ynamides with Nitrosoarene and Efficient Synthesis of 4-aminopyrimidine cores from Ynamides and Nitriles with OLED Applications
author_sort	Huang, Wei-Ching
title	Lewis acid Catalyzed Reaction of 3-En-1-Ynamides with Nitrosoarene and Efficient Synthesis of 4-aminopyrimidine cores from Ynamides and Nitriles with OLED Applications
title_short	Lewis acid Catalyzed Reaction of 3-En-1-Ynamides with Nitrosoarene and Efficient Synthesis of 4-aminopyrimidine cores from Ynamides and Nitriles with OLED Applications
title_full	Lewis acid Catalyzed Reaction of 3-En-1-Ynamides with Nitrosoarene and Efficient Synthesis of 4-aminopyrimidine cores from Ynamides and Nitriles with OLED Applications
title_fullStr	Lewis acid Catalyzed Reaction of 3-En-1-Ynamides with Nitrosoarene and Efficient Synthesis of 4-aminopyrimidine cores from Ynamides and Nitriles with OLED Applications
title_full_unstemmed	Lewis acid Catalyzed Reaction of 3-En-1-Ynamides with Nitrosoarene and Efficient Synthesis of 4-aminopyrimidine cores from Ynamides and Nitriles with OLED Applications
title_sort	lewis acid catalyzed reaction of 3-en-1-ynamides with nitrosoarene and efficient synthesis of 4-aminopyrimidine cores from ynamides and nitriles with oled applications
publishDate	2017
url	http://ndltd.ncl.edu.tw/handle/753tfy
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Lewis acid Catalyzed Reaction of 3-En-1-Ynamides with Nitrosoarene and Efficient Synthesis of 4-aminopyrimidine cores from Ynamides and Nitriles with OLED Applications

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