| Summary: | 碩士 === 國立臺灣科技大學 === 化學工程系 === 104 === This work studied the polymerization reaction of the two terminal -C=C- groups of N,N-bismaleimide-4,4-diphenylmethane (BMI) with one CH2 group and two NH groups of Barbituric acid (BTA).And use of inhibitor free radical polymerization of hydroquinone (HQ) were studied kinetics of free radical polymerization and Michael addition reaction . In addition , use one terminal -C=C- groups of 2,2,3,3-Tetrafluoropropyl methacrylate(TFPMA) with Barbituric acid (BTA) involved in the reaction and use Trimethylolpropane triacrylate(TMPTA)to promote molecular cross-linking with characteristics of polymerization of research materials.
DSC was used to obtain the reaction kinetics data, then data were used to choose the best-fit kinetics model and determine triplet kinetics parameters.And then use TGA and GPC to discuss and analyze material properties of the heat-resistant.
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