鍵結硫、一氧化碳之錳(I)或錸(I)化合物之製備:作為氫質子轉換成氫氣之 催化劑的可能性
碩士 === 國立臺東大學 === 應用科學系 === 104 === Abstract Treament of [PPN] [PPN][M(CO)5] (M=Mn or Re) was mixture containing (SPh)2 and a ligand PS2 or PS2SiMe3 [PS2=P(C6H4-2-SH)2(C6H5) ; PS2SiMe3=P(C6H3-3- SiMe3-2-SH)2(C6H5)] result in the formation of a six-coordinated metal complexes which are [PPN][MI(CO)...
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| Format: | Others |
| Language: | zh-TW |
| Published: |
2016
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| Online Access: | http://ndltd.ncl.edu.tw/cgi-bin/gs32/gsweb.cgi/login?o=dnclcdr&s=id=%22104NTTU5115003%22.&searchmode=basic |
| Summary: | 碩士 === 國立臺東大學 === 應用科學系 === 104 ===
Abstract
Treament of [PPN] [PPN][M(CO)5] (M=Mn or Re) was mixture containing (SPh)2 and a ligand PS2 or PS2SiMe3 [PS2=P(C6H4-2-SH)2(C6H5) ; PS2SiMe3=P(C6H3-3-
SiMe3-2-SH)2(C6H5)] result in the formation of a six-coordinated metal complexes which are [PPN][MI(CO)3P(C6H4-2-S)2(C6H5)] and [PPN]
[MI(CO)3P(C6H3-3-SiMe3-2S)2(C6H5)].In addition, we use rhenium(Re) as a substitute for manganese(Mn) and other ligands to form two other coordination compounds PS3=P(C6H4-2-SH)3 and PS3SiMe3=P(C6H3-3-
SiMe3-2-SH)3 named [ReI(CO)3P(C6H3-2-S)2(C6H3-2-SH)] and [ReI(CO)3P(C6H3-3-SiMe3-2-S)2(C6H3-3-SiMe3-2-SH)]。Herein, we will analyze the spectral properties and cyclic voltammetry (CV) of these complexes to explore the possibility whether it has dihydrogen production in electrochemically.
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