Application of Poly(2,2'-(1-methoxy-2-(4-vinylphenyl)ethane-1,1-diyl)dipyridine-co-N-isopropylacrylamide) (P(MVP-co-NIPAM)) in heterogeneous catalysis

碩士 === 國立清華大學 === 化學系 === 104 === Functional polymer of P(DPyVE-co-NIPAM) and P(MVP-co-NIPAM) were obtained from the copolymerization of N-isopropylacrylamide (NIPAM) and novel monomers of 1,1-di(pyridin-2-yl)-2-(4-vinylphenyl)ethan-1-ol (DPyVE) and 2,2'-(1-methoxy-2-(4-vinylphenyl)ethane-1,1-d...

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Main Authors: Chang, Hsiang Chun, 張翔竣
Other Authors: Peng, Chi How
Format: Others
Language:zh-TW
Published: 2016
Online Access:http://ndltd.ncl.edu.tw/handle/75664912853968051265
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spelling ndltd-TW-104NTHU50651132017-07-09T04:30:35Z http://ndltd.ncl.edu.tw/handle/75664912853968051265 Application of Poly(2,2'-(1-methoxy-2-(4-vinylphenyl)ethane-1,1-diyl)dipyridine-co-N-isopropylacrylamide) (P(MVP-co-NIPAM)) in heterogeneous catalysis 功能性高分子 Poly(2,2'-(1-methoxy-2-(4-vinylphenyl)ethane-1,1-diyl)dipyridine-co-N-isopropylacrylamide) (P(MVP-co-NIPAM)) 的合成以及在異相催化反應的應用 Chang, Hsiang Chun 張翔竣 碩士 國立清華大學 化學系 104 Functional polymer of P(DPyVE-co-NIPAM) and P(MVP-co-NIPAM) were obtained from the copolymerization of N-isopropylacrylamide (NIPAM) and novel monomers of 1,1-di(pyridin-2-yl)-2-(4-vinylphenyl)ethan-1-ol (DPyVE) and 2,2'-(1-methoxy-2-(4-vinylphenyl)ethane-1,1-diyl)dipyridine (MVP). The functional polymers were coordinated to copper and palladium to form heterogeneous catalysts for click reaction and Suzuki-Miyaura reaction, respectively. The polymer-metal complexes could be recycled easily through filtrating after the reactions at least five time without significant decline in catalytic efficiency. Peng, Chi How 彭之皓 2016 學位論文 ; thesis 179 zh-TW
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language zh-TW
format Others
sources NDLTD
description 碩士 === 國立清華大學 === 化學系 === 104 === Functional polymer of P(DPyVE-co-NIPAM) and P(MVP-co-NIPAM) were obtained from the copolymerization of N-isopropylacrylamide (NIPAM) and novel monomers of 1,1-di(pyridin-2-yl)-2-(4-vinylphenyl)ethan-1-ol (DPyVE) and 2,2'-(1-methoxy-2-(4-vinylphenyl)ethane-1,1-diyl)dipyridine (MVP). The functional polymers were coordinated to copper and palladium to form heterogeneous catalysts for click reaction and Suzuki-Miyaura reaction, respectively. The polymer-metal complexes could be recycled easily through filtrating after the reactions at least five time without significant decline in catalytic efficiency.
author2 Peng, Chi How
author_facet Peng, Chi How
Chang, Hsiang Chun
張翔竣
author Chang, Hsiang Chun
張翔竣
spellingShingle Chang, Hsiang Chun
張翔竣
Application of Poly(2,2'-(1-methoxy-2-(4-vinylphenyl)ethane-1,1-diyl)dipyridine-co-N-isopropylacrylamide) (P(MVP-co-NIPAM)) in heterogeneous catalysis
author_sort Chang, Hsiang Chun
title Application of Poly(2,2'-(1-methoxy-2-(4-vinylphenyl)ethane-1,1-diyl)dipyridine-co-N-isopropylacrylamide) (P(MVP-co-NIPAM)) in heterogeneous catalysis
title_short Application of Poly(2,2'-(1-methoxy-2-(4-vinylphenyl)ethane-1,1-diyl)dipyridine-co-N-isopropylacrylamide) (P(MVP-co-NIPAM)) in heterogeneous catalysis
title_full Application of Poly(2,2'-(1-methoxy-2-(4-vinylphenyl)ethane-1,1-diyl)dipyridine-co-N-isopropylacrylamide) (P(MVP-co-NIPAM)) in heterogeneous catalysis
title_fullStr Application of Poly(2,2'-(1-methoxy-2-(4-vinylphenyl)ethane-1,1-diyl)dipyridine-co-N-isopropylacrylamide) (P(MVP-co-NIPAM)) in heterogeneous catalysis
title_full_unstemmed Application of Poly(2,2'-(1-methoxy-2-(4-vinylphenyl)ethane-1,1-diyl)dipyridine-co-N-isopropylacrylamide) (P(MVP-co-NIPAM)) in heterogeneous catalysis
title_sort application of poly(2,2'-(1-methoxy-2-(4-vinylphenyl)ethane-1,1-diyl)dipyridine-co-n-isopropylacrylamide) (p(mvp-co-nipam)) in heterogeneous catalysis
publishDate 2016
url http://ndltd.ncl.edu.tw/handle/75664912853968051265
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