Application of Poly(2,2'-(1-methoxy-2-(4-vinylphenyl)ethane-1,1-diyl)dipyridine-co-N-isopropylacrylamide) (P(MVP-co-NIPAM)) in heterogeneous catalysis
碩士 === 國立清華大學 === 化學系 === 104 === Functional polymer of P(DPyVE-co-NIPAM) and P(MVP-co-NIPAM) were obtained from the copolymerization of N-isopropylacrylamide (NIPAM) and novel monomers of 1,1-di(pyridin-2-yl)-2-(4-vinylphenyl)ethan-1-ol (DPyVE) and 2,2'-(1-methoxy-2-(4-vinylphenyl)ethane-1,1-d...
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| Other Authors: | |
| Format: | Others |
| Language: | zh-TW |
| Published: |
2016
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| Online Access: | http://ndltd.ncl.edu.tw/handle/75664912853968051265 |
| Summary: | 碩士 === 國立清華大學 === 化學系 === 104 === Functional polymer of P(DPyVE-co-NIPAM) and P(MVP-co-NIPAM) were obtained from the copolymerization of N-isopropylacrylamide (NIPAM) and novel monomers of 1,1-di(pyridin-2-yl)-2-(4-vinylphenyl)ethan-1-ol (DPyVE) and 2,2'-(1-methoxy-2-(4-vinylphenyl)ethane-1,1-diyl)dipyridine (MVP). The functional polymers were coordinated to copper and palladium to form heterogeneous catalysts for click reaction and Suzuki-Miyaura reaction, respectively. The polymer-metal complexes could be recycled easily through filtrating after the reactions at least five time without significant decline in catalytic efficiency.
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