Preparation of Various Quinone Derivatives with the Assistance of Silver Carbonate via C-H Functionalization and Leads to the Formations of C-N and C-P Bonds

碩士 === 國立中興大學 === 化學系所 === 104 === In this work, the synthesis and characterization of several quinone derivatives with specific configurations were described. Stoichiometric amount of silver carbonate was employed and the C-H activation on the quinone was observed. Crystal structures of several new...

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Main Authors: Shi-Zong Huang, 黃仕宗
Other Authors: 洪豐裕
Format: Others
Language:zh-TW
Published: 2016
Online Access:http://ndltd.ncl.edu.tw/handle/b9xdm5
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spelling ndltd-TW-104NCHU50650772019-05-15T23:00:43Z http://ndltd.ncl.edu.tw/handle/b9xdm5 Preparation of Various Quinone Derivatives with the Assistance of Silver Carbonate via C-H Functionalization and Leads to the Formations of C-N and C-P Bonds 藉由碳酸銀協助透過C-H鍵活化形成具有C-N及C-P鍵的苯醌衍生物製備研究 Shi-Zong Huang 黃仕宗 碩士 國立中興大學 化學系所 104 In this work, the synthesis and characterization of several quinone derivatives with specific configurations were described. Stoichiometric amount of silver carbonate was employed and the C-H activation on the quinone was observed. Crystal structures of several newly-made quinone derivatives were determined by X-ray diffraction methods. These novel quinone derivatives having both phosphine group(s) and amine functional group(s) might act as P,N-bidentate ligands toward transition metals and form metal-containing pre-catalysts. The potential of these pre-catalysts in catalysis is worthy of exploring in the future. 洪豐裕 2016 學位論文 ; thesis 151 zh-TW
collection NDLTD
language zh-TW
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description 碩士 === 國立中興大學 === 化學系所 === 104 === In this work, the synthesis and characterization of several quinone derivatives with specific configurations were described. Stoichiometric amount of silver carbonate was employed and the C-H activation on the quinone was observed. Crystal structures of several newly-made quinone derivatives were determined by X-ray diffraction methods. These novel quinone derivatives having both phosphine group(s) and amine functional group(s) might act as P,N-bidentate ligands toward transition metals and form metal-containing pre-catalysts. The potential of these pre-catalysts in catalysis is worthy of exploring in the future.
author2 洪豐裕
author_facet 洪豐裕
Shi-Zong Huang
黃仕宗
author Shi-Zong Huang
黃仕宗
spellingShingle Shi-Zong Huang
黃仕宗
Preparation of Various Quinone Derivatives with the Assistance of Silver Carbonate via C-H Functionalization and Leads to the Formations of C-N and C-P Bonds
author_sort Shi-Zong Huang
title Preparation of Various Quinone Derivatives with the Assistance of Silver Carbonate via C-H Functionalization and Leads to the Formations of C-N and C-P Bonds
title_short Preparation of Various Quinone Derivatives with the Assistance of Silver Carbonate via C-H Functionalization and Leads to the Formations of C-N and C-P Bonds
title_full Preparation of Various Quinone Derivatives with the Assistance of Silver Carbonate via C-H Functionalization and Leads to the Formations of C-N and C-P Bonds
title_fullStr Preparation of Various Quinone Derivatives with the Assistance of Silver Carbonate via C-H Functionalization and Leads to the Formations of C-N and C-P Bonds
title_full_unstemmed Preparation of Various Quinone Derivatives with the Assistance of Silver Carbonate via C-H Functionalization and Leads to the Formations of C-N and C-P Bonds
title_sort preparation of various quinone derivatives with the assistance of silver carbonate via c-h functionalization and leads to the formations of c-n and c-p bonds
publishDate 2016
url http://ndltd.ncl.edu.tw/handle/b9xdm5
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