Preparation of Various Quinone Derivatives with the Assistance of Silver Carbonate via C-H Functionalization and Leads to the Formations of C-N and C-P Bonds
碩士 === 國立中興大學 === 化學系所 === 104 === In this work, the synthesis and characterization of several quinone derivatives with specific configurations were described. Stoichiometric amount of silver carbonate was employed and the C-H activation on the quinone was observed. Crystal structures of several new...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Others |
| Language: | zh-TW |
| Published: |
2016
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| Online Access: | http://ndltd.ncl.edu.tw/handle/b9xdm5 |
| Summary: | 碩士 === 國立中興大學 === 化學系所 === 104 === In this work, the synthesis and characterization of several quinone derivatives with specific configurations were described. Stoichiometric amount of silver carbonate was employed and the C-H activation on the quinone was observed. Crystal structures of several newly-made quinone derivatives were determined by X-ray diffraction methods. These novel quinone derivatives having both phosphine group(s) and amine functional group(s) might act as P,N-bidentate ligands toward transition metals and form metal-containing pre-catalysts. The potential of these pre-catalysts in catalysis is worthy of exploring in the future.
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