Self-Assembly Synthesis of a [4]Rotacatenane

碩士 === 國立臺灣大學 === 化學研究所 === 103 === Recently, we demonstrated that the threading of oligo(ethylene glyco) and urea units into bis-para-xylyl[26]crown-6 (BPX26C6) via Na+ ion template is possible. Herein, we reported a single urea functionality in a dumbbell-shaped guest can be “clipped” by macrocycl...

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Main Authors:	Cheng-Fu Fan, 范承甫
Other Authors:	Sheng-Hsien Chiu
Format:	Others
Language:	zh-TW
Published:	2015
Online Access:	http://ndltd.ncl.edu.tw/handle/66437107296954043259

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spelling	ndltd-TW-103NTU050650922016-11-19T04:09:56Z http://ndltd.ncl.edu.tw/handle/66437107296954043259 Self-Assembly Synthesis of a [4]Rotacatenane [4]車輪交環烷的自組裝合成研究 Cheng-Fu Fan 范承甫碩士國立臺灣大學化學研究所 103 Recently, we demonstrated that the threading of oligo(ethylene glyco) and urea units into bis-para-xylyl[26]crown-6 (BPX26C6) via Na+ ion template is possible. Herein, we reported a single urea functionality in a dumbbell-shaped guest can be “clipped” by macrocycle generated from a diamine and two dialdehydes through the templating effect of a Na+ ion to self-assembly of a [4]rotacatenane. The resulting imine-containing rotacatenane can be reduced to allow isolation of stable amine-based rotacatenane. Sheng-Hsien Chiu 邱勝賢 2015 學位論文 ; thesis 51 zh-TW
collection	NDLTD
language	zh-TW
format	Others
sources	NDLTD
description	碩士 === 國立臺灣大學 === 化學研究所 === 103 === Recently, we demonstrated that the threading of oligo(ethylene glyco) and urea units into bis-para-xylyl[26]crown-6 (BPX26C6) via Na+ ion template is possible. Herein, we reported a single urea functionality in a dumbbell-shaped guest can be “clipped” by macrocycle generated from a diamine and two dialdehydes through the templating effect of a Na+ ion to self-assembly of a [4]rotacatenane. The resulting imine-containing rotacatenane can be reduced to allow isolation of stable amine-based rotacatenane.
author2	Sheng-Hsien Chiu
author_facet	Sheng-Hsien Chiu Cheng-Fu Fan 范承甫
author	Cheng-Fu Fan 范承甫
spellingShingle	Cheng-Fu Fan 范承甫 Self-Assembly Synthesis of a [4]Rotacatenane
author_sort	Cheng-Fu Fan
title	Self-Assembly Synthesis of a [4]Rotacatenane
title_short	Self-Assembly Synthesis of a [4]Rotacatenane
title_full	Self-Assembly Synthesis of a [4]Rotacatenane
title_fullStr	Self-Assembly Synthesis of a [4]Rotacatenane
title_full_unstemmed	Self-Assembly Synthesis of a [4]Rotacatenane
title_sort	self-assembly synthesis of a [4]rotacatenane
publishDate	2015
url	http://ndltd.ncl.edu.tw/handle/66437107296954043259
work_keys_str_mv	AT chengfufan selfassemblysynthesisofa4rotacatenane AT fànchéngfǔ selfassemblysynthesisofa4rotacatenane AT chengfufan 4chēlúnjiāohuánwándezìzǔzhuānghéchéngyánjiū AT fànchéngfǔ 4chēlúnjiāohuánwándezìzǔzhuānghéchéngyánjiū
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Self-Assembly Synthesis of a [4]Rotacatenane

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