Discussing the structure of crystal, spectroscopy and magnetic properties of M1 = Co, (por)1 = (2-NC3H5-21-CH2C6H5-NCTPP) and (2-NC3H5-21-Y-CH2C6H4CH3-NCTPP) (Y = o, m, p), (L) = Cl；M2 = Zn, (por)2 = (2-NC3H5-H-NCTPP), (L) = Cl

Discussing the structure of crystal, spectroscopy and magnetic properties of M1 = Co, (por)1 = (2-NC3H5-21-CH2C6H5-NCTPP) and (2-NC3H5-21-Y-CH2C6H4CH3-NCTPP) (Y = o, m, p), (L) = Cl；M2 = Zn, (por)2 = (2-NC3H5-H-NCTPP), (L) = Cl

碩士 === 國立中興大學 === 化學系所 === 103 === The inner C-benzyl- and C-o-xylyl (or m-xylyl, p-xylyl)-substituted cobalt(II) complexes of a 2-N-substituted N-confused porphyrin were synthesized from the reaction of 2-NC3H5NCTPPH (1) and CoCl2•6H2O in toluene (or o-xylene, m-xylene, p-xylene), and the structure...

Full description

Bibliographic Details
Main Authors:	Ya-Yuan Lai, 賴亞元
Other Authors:	Jyh-Horung Chen
Format:	Others
Language:	zh-TW
Published:	2015
Online Access:	http://ndltd.ncl.edu.tw/handle/20638416637525508514

Similar Items

Metal complexes of M(2-NCH2COOCH2C6H5NCTPP) (M = Ni2+, Pd2+, Pt2+), Mn(2-NCH2COOCH2C6H5NCTPP)Br andCo(2-NCH2COOCH2C6H5-21-R-NCTPP)Cl (R = CH2C6H5, CH2C6H4CH3)
by: Yu-Cheng Wang, et al.
Published: (2013)

Discussion on the crystal structures、spectroscopies and magnetic properties of Pt(2-NCH2C6H5NCTPP)、Co(2-NCH2C6H5-21-CH2C6H5NCTPP)Cl、 Co(2-NCH2C6H5-21-CN-NCTPP)(NCS) and Pd(2-NCH2-p-C6H4CH2ClNCTPP)、Co(2-NCH2-p-C6H4CH2XNCTPP)Cl (X = Cl, Br)
by: Siou-Shen Li, et al.
Published: (2016)

Discussion on the crystal structures, spectroscopies and magnetic properties of Hg(2-NCH2-p-C6H4CH3NCTPP)I、Co(2-NCH2-p-C6H4CH3-21-CH2-m-C6H4CH3NCTPP)X, (X：Cl、NCS)、Co(2-NCH2-p-C6H4CH3-21-CH2C6H5NCTPP)(NCS)
by: Chun-Yeh Lin, et al.
Published: (2017)

Discussing the structure of crystal, spectroscopy and magnetic properties of M(2-NCH2-o-C6H4-CH2ClNCTPP)(M = Pd, Pt) and Co(2-NCH2-o-C6H4-CH2Cl-21-CH2C6H5NCTPP)X, (X = Cl, Br)
by: Yu-Qi Liu 劉宥圻, et al.
Published: (2016)

Using the structure of crystal and spectroscopy to discuss the metal complexes of 2-N substituted N-confused porphyrin : Zn(2-NCH2COOCH2C6H5-21-H-NCTPP)Cl and Co(2-NCH2COOCH2C6H5-21-o-CH2C6H4CH3NCTPP)Cl
by: Jyun- Fan Wu, et al.
Published: (2015)

Metal complexes of 2-aza-2-(p-methylbenyl)-5, 10, 15, 20-tetraphenyl-21-carbaporphyrin : Ni(2-NCH2-p-C6H4CH3NCTPP) andCo(2-NCH2-p-C6H4CH3-21-CH2-o-C6H4CH3NCTPP)Cl
by: Hsueh-Ju Li, et al.
Published: (2014)

Reaction, magnetic properties , spectroscopies and crystal structures of Hg(2-NCH3NCTPPH)Cl、Co(2-NCH3-21-CNNCTPP)(NCS)、Co(2-NCH3-21-CH2C6H5NCTPP)Cl
by: Wei-Joe Tsai, et al.
Published: (2018)

Synthesis and characterization of metal complexes：Hg(2-NCH2-p-C6H4-isoC3H7NCTPPH)I, Co(2-NCH2-p-C6H4-isoC3H7-21-CH2-o-C6H4CH3-NCTPP)Cl, Hg(2-NCH2COOCH2C6H5NCTPPH)I, Hg(2-NCH2COOCH2C6H5NCTPPH)Cl and Co(2-NCH2COOCH3-21-CN-NCTPP)(NCS).
by: Hsiang-Yin Lin, et al.
Published: (2017)

Synthesis and characterization of metal complexes: 2-aza-2-[p-(isopropyl)benzyl]-5,10,15,20-tetraphenyl-21-carbaporphyrin: M(2-NCH2-p-C6H4-isoC3H7NCTPP) (M = Ni2+, Pd2+, Pt2+) and Chloro(2-aza-2-[p-(isopropyl)benzyl]-5,10,15,20-tetraphenyl-21- p-xylyl-21-carbaporphyrinato-N,N′,N′′) cobalt(II): Co(2-NCH2-p-C6H4-isoC3H7-21-CH2-p-C6H4CH3-NCTPP)Cl
by: Chun-Chia Chiu, et al.
Published: (2014)

Metal complexes of 2-aza-2-(p-cyanobenzyl)-5,10,15,20-tetraphenyl-21-carbaporphyrin:M(2-NCH2-p-C6H4-CNNCTPP)(M=Ni2+,Pt2+ )、Cu(2-NCH2-p-C6H4-CNNCTPPO) andCo(2-NCH2-p-C6H4-CN-21-CH2C6H4CH3NCTPP)Cl
by: Ming-Yu Chen, et al.
Published: (2013)

Synthesis and characterization of metal complexes：Co(2-NCH2COOCH2CH3-21-CH2C6H5NCTPP)Cl,Co(2-NCH2COOCH2CH3-21-CNNCTPP)(NCS), Hg(2-NCH2COOCH2CH3NCTPPH)Cl, Hg(2-NCH2COOCH2CH3NCTPPH)Br and Hg(2-NCH2COOCH2CH3NCTPPH)I.
by: Ta-Kang Liu, et al.
Published: (2018)

Crystal structure of pentachloro(propionitrile)tantalum(V), TaCl5(NC-CH2-CH3) and of pentachloro(propionitrile)niobium(V), NbCl5(NC-CH2-CH3)
by: Abdelhalim-Ahmed Ibrahim, et al.
Published: (1999-03-01)

Crystal structure of pentachloro(3,3'-thiodipropionitrile)tantalum(V), TaCl5[NC(CH2)2S(CH2)2CN] and of pentachloro(3,3'-thiodipropionitrile) niobium(V), NbCl5[NC(CH2)2S(CH2)2CN]
by: Abdelhalim-Ahmed Ibrahim, et al.
Published: (1999-03-01)

Using the spectroscopy and the structure of crystal to discuss the Metalloporphyrins M1=Cu、Ni，por1=(N-p-NSO2C6H4OCH3–tpp); M2=Ag，por2=(2-NCH2 CH=CH2-3-OCH3NCTPP)
by: Hung-Yi Lin, et al.
Published: (2011)

Magnetic Properties in High-Spin Mononuclear Manganese (III) of Inverted N-Allylated Porphyrin Complexes : Trans-Mn(2-NCH2CH=CH2NCTPP)Br versusCis-Zn(2-NCH2=CH-CH2NCTPP)Cl and synthesisof Cu porphyrin complex.
by: Ming-Yang Tsai, et al.
Published: (2010)

Crystal structure of methylammonium sulfanilate, (CH3NH3)H2NC6H4SO3
by: Schreuer J.
Published: (1999-09-01)

Crystal structure of benzyltriphenylphosphonium chloride, (C6H5)CH2P(C6H5)3Cl
by: Fischer A., et al.
Published: (1997-12-01)

Crystal structure of benzyltriphenylphosphonium chloride, (C6H5)CH2P(C6H5)3Cl
by: Fischer A., et al.
Published: (1997-12-01)

Crystal structure of 3,4-dihydro-2,2,4-trimethyl-3-(N-phenylimino)-2H-1,4-benzoxazine,(CH3)3(NC6H5)C8H4NO
by: Peters K., et al.
Published: (1998-04-01)

Crystal structure of benzyltrimethylammonium dithiobenzoate, [C6H5CH2N(CH3)3][C6H5CS2]
by: Mahjoub A.
Published: (2005-04-01)

Crystal structure of(6S)-6-[(1R,2S,5R)-(-)-2-isopropyl-5-methyl-cyciohexyloxy]-3-phenyl-6H-1,2-oxazine,[ONC(CH)3(C6H5)O(CH)2(CH2)2CHCH2CH(CH3)2CH3]
by: Jaenicke-Roessler U., et al.
Published: (1998-04-01)

The study of magnetic property in the high-spin mononuclear manganese (III) of inverted N-confused porphyrin complexe, Mn(2-NCH2-p-C6H4-CO2CH3NCTPP)Br
by: Chen Yang, et al.
Published: (2011)

Crystal structure of 1-(2'-benzoyl-4',6'-dimethylphenyl)-2-methylnaphthaline,[C10H6CH3][C6H2(OCH2C6H5)(CH3)2]
by: Peters Κ., et al.
Published: (1999-12-01)

Crystal structure of aquaphenanthroline(pyridine-2,6-dicarboxylato)- cobalt(II) pyridine-2,6-dicarboxylic acid monosolvate tetrahydrate, [Co(H2O)(C12H8N2){NC5H3(COO)2}] · NC5H3(COOH)2 · 4H2O
by: Su H., et al.
Published: (2005-04-01)

Metal Complexes of 2-N substituted N-confused Porphyrin: PartⅠ:Comparism of iminiun ion pairs type between 2-NCH2CH2CH2OC6H5NCTPPH and Ni(2-NCH2CH2CH2OC6H5NCTPP)PartⅡ: Molecular structures of Cu(Ⅱ), Rh(Ⅲ) complexes of 2-N substituted N-confused porphyrin inner C-oxide
by: Wen-Chain Lin, et al.
Published: (2012)

Crystal structure of (η5 -cyclopentadienyl)(2-allyl-3-methyl-4-methylene-1-aza-3-azonia-2-butene-1,4-diyl)(dimethylphenylphosphane)cobalt(in) hexafluorophosphate,C5H5CO(CH3)(CH2)(C3H5)C2N2H[P(C6H5)(CH3)2]PF6
by: Peters K., et al.
Published: (1998-04-01)

MIXED-LIGANDS μ3-OXO TRINUCLEAR CARBOXYLATES [Fe3O(CH2BrCOO)1.5(CH2ClCOO)4.5(H2O)3]Br0.75Cl0.25 5H2O and [Fe3O(BrCH2COO)6(H2O)3] NO3⋅2.63H2O
by: Sergiu Shova, et al.
Published: (2008-12-01)

Crystal structure of ethyldimethylphenylammonium triiodide,[(C2H5)(CH3)2(C6H5)N]I3
by: Reuter H., et al.
Published: (1998-04-01)

Crystal structure of (phenyl) (piperidino) (dicyclohexylamino)-phoshiniminocyclotrithiazene dichloromethane hemisolvate, ((C6H5)N(C6H11)2)(C5H10)PN(S3N3))2(CH2Cl2)
by: Srinivas Janaswamy, et al.
Published: (1997-12-01)

Crystal structure of 4,5-dimethyl-2-(4-methylpiperazin-1-yl)-3-phenacyl-imidazole,C3N2(CH3)2(CH2COC6H5)[C4H8N2(CH3)]H2O
by: Peters K., et al.
Published: (1998-04-01)

Synthesis, structure, semiconductive and photoluminescent properties of [{Eu(NC5H4COOH)3(H2O)2}(1.5ZnCl4)·(2H2O)]n
by: Chen Wen-Tong, et al.
Published: (2009-01-01)

Synthesis, structure, semiconductive and photoluminescent properties of [{Eu(NC5H4COOH)3(H2O)2}(1.5ZnCl4)•(2H2O)]n
by: YA-PING XU, et al.
Published: (2009-07-01)

Crystal structure of 1,1 -(1,3-propanediyl)bis(4-cyano)pyridiniuiii dibromide, [NC-C5H4N-C3H6-NC5H4-CN]Br2
by: Inkmann E., et al.
Published: (1997-12-01)

Crystal structure of rubidium sulfanilate sesquihydrate, RbH2NC6H4SO3 ∙ 1.5H2O
by: Schreuer J.
Published: (1999-06-01)

Crystal structure of thallium sulfanilate semihydrate, TlH2NC6H4SO3 0.5H2O
by: Schreuer J.
Published: (1999-09-01)

Crystal structure of E,E-2,5-di-(2-carbomethoxystyryl)thiophene, ((C6H5)C(C00CH3)CH)2C4H2S
by: Nagl A., et al.
Published: (1997-12-01)

Crystal structure of E,E-2,5-di-(2-carbomethoxystyryl)thiophene, ((C6H5)C(C00CH3)CH)2C4H2S
by: Nagl A., et al.
Published: (1997-12-01)

Crystal structure of (cyclohexanonetriphenylphosphonium) (trichlorotriphenyl)palladate(II)-benzene (1/1), (C6H5)3P(CHCH2CO(CH2)3)][(C6H5)3PPdCl3] · C6H6
by: Casellato U., et al.
Published: (2000-03-01)

Theoretical studies on the keto enol intramolecular tautomerism of some acetyl derivatives ,CH3COR,(R=H ,F,Cl,OH,CN,NC,BH2,NH2, CH3)
by: Chen-Chang Wu, et al.

Theoretical studies on the keto enol intramolecular tautomerism of some acetyl derivatives ,CH3COR,(R=H ,F,Cl,OH,CN,NC,BH2,NH2, CH3)
by: Wu, Cheng-Cang, et al.
Published: (1993)