Discussing the structure of crystal, spectroscopy and magnetic properties of M1 = Co, (por)1 = (2-NC3H5-21-CH2C6H5-NCTPP) and (2-NC3H5-21-Y-CH2C6H4CH3-NCTPP) (Y = o, m, p), (L) = Cl；M2 = Zn, (por)2 = (2-NC3H5-H-NCTPP), (L) = Cl

Discussing the structure of crystal, spectroscopy and magnetic properties of M1 = Co, (por)1 = (2-NC3H5-21-CH2C6H5-NCTPP) and (2-NC3H5-21-Y-CH2C6H4CH3-NCTPP) (Y = o, m, p), (L) = Cl；M2 = Zn, (por)2 = (2-NC3H5-H-NCTPP), (L) = Cl

碩士 === 國立中興大學 === 化學系所 === 103 === The inner C-benzyl- and C-o-xylyl (or m-xylyl, p-xylyl)-substituted cobalt(II) complexes of a 2-N-substituted N-confused porphyrin were synthesized from the reaction of 2-NC3H5NCTPPH (1) and CoCl2•6H2O in toluene (or o-xylene, m-xylene, p-xylene), and the structure...

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Main Authors: Ya-Yuan Lai, 賴亞元
Other Authors: Jyh-Horung Chen
Format: Others
Language:zh-TW
Published: 2015
Online Access:http://ndltd.ncl.edu.tw/handle/20638416637525508514
id ndltd-TW-103NCHU5065035
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spelling ndltd-TW-103NCHU50650352017-03-26T04:24:14Z http://ndltd.ncl.edu.tw/handle/20638416637525508514 Discussing the structure of crystal, spectroscopy and magnetic properties of M1 = Co, (por)1 = (2-NC3H5-21-CH2C6H5-NCTPP) and (2-NC3H5-21-Y-CH2C6H4CH3-NCTPP) (Y = o, m, p), (L) = Cl；M2 = Zn, (por)2 = (2-NC3H5-H-NCTPP), (L) = Cl 探討金屬錯化合物M(por)(L)之晶體結構、光譜及磁性；M1=鈷，(por)1=(2-NC3H5-21-CH2C6H5-NCTPP)和(2-NC3H5-21-Y-CH2C6H4CH3-NCTPP)(Y=o,m,p)，(L)=Cl；M2=鋅，(por)2=(2-NC3H5-H-NCTPP)，(L)=Cl Ya-Yuan Lai 賴亞元 碩士 國立中興大學 化學系所 103 The inner C-benzyl- and C-o-xylyl (or m-xylyl, p-xylyl)-substituted cobalt(II) complexes of a 2-N-substituted N-confused porphyrin were synthesized from the reaction of 2-NC3H5NCTPPH (1) and CoCl2•6H2O in toluene (or o-xylene, m-xylene, p-xylene), and the structures were revealed by single-crystal X-ray analysis.The axial zero-field splitting parameter D was found to vary from 46.9 cm-1 in 2 to 42.0 cm-1 in 3, 34.7 cm-1 in 4 and 35.6 cm-1 in 5 by paramagnetic susceptibility measurements. The magnitude of D can be related to the coordination sphere at the cobalt sites. Jyh-Horung Chen 陳志鴻 2015 學位論文 ; thesis 88 zh-TW
collection NDLTD
language zh-TW
format Others
sources NDLTD
description 碩士 === 國立中興大學 === 化學系所 === 103 === The inner C-benzyl- and C-o-xylyl (or m-xylyl, p-xylyl)-substituted cobalt(II) complexes of a 2-N-substituted N-confused porphyrin were synthesized from the reaction of 2-NC3H5NCTPPH (1) and CoCl2•6H2O in toluene (or o-xylene, m-xylene, p-xylene), and the structures were revealed by single-crystal X-ray analysis.The axial zero-field splitting parameter D was found to vary from 46.9 cm-1 in 2 to 42.0 cm-1 in 3, 34.7 cm-1 in 4 and 35.6 cm-1 in 5 by paramagnetic susceptibility measurements. The magnitude of D can be related to the coordination sphere at the cobalt sites.
author2 Jyh-Horung Chen
author_facet Jyh-Horung Chen
Ya-Yuan Lai
賴亞元
author Ya-Yuan Lai
賴亞元
spellingShingle Ya-Yuan Lai
賴亞元
Discussing the structure of crystal, spectroscopy and magnetic properties of M1 = Co, (por)1 = (2-NC3H5-21-CH2C6H5-NCTPP) and (2-NC3H5-21-Y-CH2C6H4CH3-NCTPP) (Y = o, m, p), (L) = Cl；M2 = Zn, (por)2 = (2-NC3H5-H-NCTPP), (L) = Cl
author_sort Ya-Yuan Lai
title Discussing the structure of crystal, spectroscopy and magnetic properties of M1 = Co, (por)1 = (2-NC3H5-21-CH2C6H5-NCTPP) and (2-NC3H5-21-Y-CH2C6H4CH3-NCTPP) (Y = o, m, p), (L) = Cl；M2 = Zn, (por)2 = (2-NC3H5-H-NCTPP), (L) = Cl
title_short Discussing the structure of crystal, spectroscopy and magnetic properties of M1 = Co, (por)1 = (2-NC3H5-21-CH2C6H5-NCTPP) and (2-NC3H5-21-Y-CH2C6H4CH3-NCTPP) (Y = o, m, p), (L) = Cl；M2 = Zn, (por)2 = (2-NC3H5-H-NCTPP), (L) = Cl
title_full Discussing the structure of crystal, spectroscopy and magnetic properties of M1 = Co, (por)1 = (2-NC3H5-21-CH2C6H5-NCTPP) and (2-NC3H5-21-Y-CH2C6H4CH3-NCTPP) (Y = o, m, p), (L) = Cl；M2 = Zn, (por)2 = (2-NC3H5-H-NCTPP), (L) = Cl
title_fullStr Discussing the structure of crystal, spectroscopy and magnetic properties of M1 = Co, (por)1 = (2-NC3H5-21-CH2C6H5-NCTPP) and (2-NC3H5-21-Y-CH2C6H4CH3-NCTPP) (Y = o, m, p), (L) = Cl；M2 = Zn, (por)2 = (2-NC3H5-H-NCTPP), (L) = Cl
title_full_unstemmed Discussing the structure of crystal, spectroscopy and magnetic properties of M1 = Co, (por)1 = (2-NC3H5-21-CH2C6H5-NCTPP) and (2-NC3H5-21-Y-CH2C6H4CH3-NCTPP) (Y = o, m, p), (L) = Cl；M2 = Zn, (por)2 = (2-NC3H5-H-NCTPP), (L) = Cl
title_sort discussing the structure of crystal, spectroscopy and magnetic properties of m1 = co, (por)1 = (2-nc3h5-21-ch2c6h5-nctpp) and (2-nc3h5-21-y-ch2c6h4ch3-nctpp) (y = o, m, p), (l) = cl；m2 = zn, (por)2 = (2-nc3h5-h-nctpp), (l) = cl
publishDate 2015
url http://ndltd.ncl.edu.tw/handle/20638416637525508514
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