To Study the Free Radical Addition Cyclization Reactions of the Tosyl Radical with Asymmetric Diene Compound and to Investigate the Regioselectivity and Stereoselectivity

碩士 === 義守大學 === 化學工程學系暨生物技術與化學工程研究所 === 103 === In recent years, it is important that the application of free radical in organic synthesis, especially, the regioselectivity and the stereoselectivity of the free radical addition cyclization reactions. It were investigated that the regioselectivity a...

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Main Authors:	Chia-Yu Lu, 呂嘉瑜
Other Authors:	Yuh-Wern Wu
Format:	Others
Language:	zh-TW
Published:	2015
Online Access:	http://ndltd.ncl.edu.tw/handle/88571705739719147614

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spelling	ndltd-TW-103ISU050630112016-12-04T04:07:59Z http://ndltd.ncl.edu.tw/handle/88571705739719147614 To Study the Free Radical Addition Cyclization Reactions of the Tosyl Radical with Asymmetric Diene Compound and to Investigate the Regioselectivity and Stereoselectivity 利用對甲苯磺醯基自由基與不對稱二烯化合物進行自由基加成環化反應探討其位向選擇性與立體選擇性 Chia-Yu Lu 呂嘉瑜碩士義守大學化學工程學系暨生物技術與化學工程研究所 103 In recent years, it is important that the application of free radical in organic synthesis, especially, the regioselectivity and the stereoselectivity of the free radical addition cyclization reactions. It were investigated that the regioselectivity and stereoselectivity of the reactions of the toluene sulfonyl radical with asymmetric dienes, (2-methyl propenyl)-(4-bromo-2-butenyl) ether and E-4-bromobut-2-enyl acrylate by the substituent polar effect and steric effect and by the different polarity of free radicals. Yuh-Wern Wu 吳裕文 2015 學位論文 ; thesis 102 zh-TW
collection	NDLTD
language	zh-TW
format	Others
sources	NDLTD
description	碩士 === 義守大學 === 化學工程學系暨生物技術與化學工程研究所 === 103 === In recent years, it is important that the application of free radical in organic synthesis, especially, the regioselectivity and the stereoselectivity of the free radical addition cyclization reactions. It were investigated that the regioselectivity and stereoselectivity of the reactions of the toluene sulfonyl radical with asymmetric dienes, (2-methyl propenyl)-(4-bromo-2-butenyl) ether and E-4-bromobut-2-enyl acrylate by the substituent polar effect and steric effect and by the different polarity of free radicals.
author2	Yuh-Wern Wu
author_facet	Yuh-Wern Wu Chia-Yu Lu 呂嘉瑜
author	Chia-Yu Lu 呂嘉瑜
spellingShingle	Chia-Yu Lu 呂嘉瑜 To Study the Free Radical Addition Cyclization Reactions of the Tosyl Radical with Asymmetric Diene Compound and to Investigate the Regioselectivity and Stereoselectivity
author_sort	Chia-Yu Lu
title	To Study the Free Radical Addition Cyclization Reactions of the Tosyl Radical with Asymmetric Diene Compound and to Investigate the Regioselectivity and Stereoselectivity
title_short	To Study the Free Radical Addition Cyclization Reactions of the Tosyl Radical with Asymmetric Diene Compound and to Investigate the Regioselectivity and Stereoselectivity
title_full	To Study the Free Radical Addition Cyclization Reactions of the Tosyl Radical with Asymmetric Diene Compound and to Investigate the Regioselectivity and Stereoselectivity
title_fullStr	To Study the Free Radical Addition Cyclization Reactions of the Tosyl Radical with Asymmetric Diene Compound and to Investigate the Regioselectivity and Stereoselectivity
title_full_unstemmed	To Study the Free Radical Addition Cyclization Reactions of the Tosyl Radical with Asymmetric Diene Compound and to Investigate the Regioselectivity and Stereoselectivity
title_sort	to study the free radical addition cyclization reactions of the tosyl radical with asymmetric diene compound and to investigate the regioselectivity and stereoselectivity
publishDate	2015
url	http://ndltd.ncl.edu.tw/handle/88571705739719147614
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To Study the Free Radical Addition Cyclization Reactions of the Tosyl Radical with Asymmetric Diene Compound and to Investigate the Regioselectivity and Stereoselectivity

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