1,6- and 1,7-Regioisomers of Dicyano-Substituted Perylene Bisimides: Synthesis,Optical and Electrochemical Properties

1,6- and 1,7-Regioisomers of Dicyano-Substituted Perylene Bisimides: Synthesis,Optical and Electrochemical Properties

碩士 === 逢甲大學 === 化學工程學系 === 103 === In this study, 1,6- and 1,7-regioisomers of dicyano-substituted perylene bisimides (1,6-C and 1,7-C) were synthesized and successfully isolated from their regioisomeric mixture using conventional methods of separation, and subsequently characterized by 400 MHz 1H N...

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Main Author: 林啟維
Other Authors: 陳奎佑
Format: Others
Language:zh-TW
Published: 2015
Online Access:http://ndltd.ncl.edu.tw/handle/uy2336
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spelling ndltd-TW-103FCU050630732019-05-15T22:25:30Z http://ndltd.ncl.edu.tw/handle/uy2336 1,6- and 1,7-Regioisomers of Dicyano-Substituted Perylene Bisimides: Synthesis,Optical and Electrochemical Properties 1,6-與 1,7-雙氰基取代苝二醯亞胺之合成、 光學與電化學性質 林啟維 碩士 逢甲大學 化學工程學系 103 In this study, 1,6- and 1,7-regioisomers of dicyano-substituted perylene bisimides (1,6-C and 1,7-C) were synthesized and successfully isolated from their regioisomeric mixture using conventional methods of separation, and subsequently characterized by 400 MHz 1H NMR spectroscopy. This is the first time that the 1,6-dicyanoperylene bisimide (1,6-C) has been obtained in pure form. Moreover, the optical and electrochemical properties of 1,6-C and 1,7-C were found to be virtually similar. Time-dependent density functional theory calculation performed on both dyes is reported in order to rationalize their electronic structures and optical properties. 陳奎佑 2015 學位論文 ; thesis 23 zh-TW
collection NDLTD
language zh-TW
format Others
sources NDLTD
description 碩士 === 逢甲大學 === 化學工程學系 === 103 === In this study, 1,6- and 1,7-regioisomers of dicyano-substituted perylene bisimides (1,6-C and 1,7-C) were synthesized and successfully isolated from their regioisomeric mixture using conventional methods of separation, and subsequently characterized by 400 MHz 1H NMR spectroscopy. This is the first time that the 1,6-dicyanoperylene bisimide (1,6-C) has been obtained in pure form. Moreover, the optical and electrochemical properties of 1,6-C and 1,7-C were found to be virtually similar. Time-dependent density functional theory calculation performed on both dyes is reported in order to rationalize their electronic structures and optical properties.
author2 陳奎佑
author_facet 陳奎佑
林啟維
author 林啟維
spellingShingle 林啟維
1,6- and 1,7-Regioisomers of Dicyano-Substituted Perylene Bisimides: Synthesis,Optical and Electrochemical Properties
author_sort 林啟維
title 1,6- and 1,7-Regioisomers of Dicyano-Substituted Perylene Bisimides: Synthesis,Optical and Electrochemical Properties
title_short 1,6- and 1,7-Regioisomers of Dicyano-Substituted Perylene Bisimides: Synthesis,Optical and Electrochemical Properties
title_full 1,6- and 1,7-Regioisomers of Dicyano-Substituted Perylene Bisimides: Synthesis,Optical and Electrochemical Properties
title_fullStr 1,6- and 1,7-Regioisomers of Dicyano-Substituted Perylene Bisimides: Synthesis,Optical and Electrochemical Properties
title_full_unstemmed 1,6- and 1,7-Regioisomers of Dicyano-Substituted Perylene Bisimides: Synthesis,Optical and Electrochemical Properties
title_sort 1,6- and 1,7-regioisomers of dicyano-substituted perylene bisimides: synthesis,optical and electrochemical properties
publishDate 2015
url http://ndltd.ncl.edu.tw/handle/uy2336
work_keys_str_mv AT línqǐwéi 16and17regioisomersofdicyanosubstitutedperylenebisimidessynthesisopticalandelectrochemicalproperties
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