Intramolecular Cyclization Reaction of Aryl Propargyl Acetate Containing Ketone Functionality with Ruthenium Chloride Complex and Oxygenation of Subsequent Ruthenium Carbene Complex
碩士 === 國立臺灣大學 === 化學研究所 === 102 === Intramolecular cyclization of propargyl acetate 1 containing a carbonyl group on the aryl ring induced by [Ru]Cl has been investigated. The reaction gives rise to the ruthenium carbene complex 2a in the presence of NH4PF6 in dichloromethane via an exo-dig cyclizat...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Others |
| Language: | en_US |
| Published: |
2014
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| Online Access: | http://ndltd.ncl.edu.tw/handle/72245166068794214537 |