Synthesis of Photochemical and Fluorescent NO-Releasing Molecule-RREs(Roussin’s Red Esters) Conjugating with Coumarin 343 as a Chromophore

Synthesis of Photochemical and Fluorescent NO-Releasing Molecule-RREs(Roussin’s Red Esters) Conjugating with Coumarin 343 as a Chromophore

碩士 === 國立嘉義大學 === 應用化學系研究所 === 102 === In this thesis, the ALA was used as a linker and conjugated with coumarin 343 to synthesize fluorescent Roussin’s red esters 1, 2 and 3. All complexes were identified by IR, ESI-MS, and UV/vis spectroscopy. Complexes 1, 2, and 3 released NO under UV irradiation...

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Main Author: 林俊源
Other Authors: 邱秀貞
Format: Others
Language:zh-TW
Online Access:http://ndltd.ncl.edu.tw/handle/92764370831597339921
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spelling ndltd-TW-102NCYU55000172016-03-09T04:30:46Z http://ndltd.ncl.edu.tw/handle/92764370831597339921 Synthesis of Photochemical and Fluorescent NO-Releasing Molecule-RREs(Roussin’s Red Esters) Conjugating with Coumarin 343 as a Chromophore 合成具有一氧化氮釋放能力及螢光性質Coumarin 343之硫辛酸為配位基之Roussin’s Red Esters 林俊源 碩士 國立嘉義大學 應用化學系研究所 102 In this thesis, the ALA was used as a linker and conjugated with coumarin 343 to synthesize fluorescent Roussin’s red esters 1, 2 and 3. All complexes were identified by IR, ESI-MS, and UV/vis spectroscopy. Complexes 1, 2, and 3 released NO under UV irradiation and the stoichiometry ratio Δ[NO]/Δ[1], Δ[NO]/Δ[2], Δ[NO]/Δ[3] = 2.06 ± 0.05, 3.09 ± 0.06 and 3.56 ± 0.20, respectively. The rate constant of NO release by complexes 1, 2, 3 under UV were determined in THF as 2.0 × 10 –4 s−1, 3.0 × 10 –4 s−1 and 6.0 × 10 –4 s−1. In addition, complexs 1, 2, and 3 released NO under blue light. All complexes cleaved DNA under UV irradiation. 邱秀貞 學位論文 ; thesis 0 zh-TW
collection NDLTD
language zh-TW
format Others
sources NDLTD
description 碩士 === 國立嘉義大學 === 應用化學系研究所 === 102 === In this thesis, the ALA was used as a linker and conjugated with coumarin 343 to synthesize fluorescent Roussin’s red esters 1, 2 and 3. All complexes were identified by IR, ESI-MS, and UV/vis spectroscopy. Complexes 1, 2, and 3 released NO under UV irradiation and the stoichiometry ratio Δ[NO]/Δ[1], Δ[NO]/Δ[2], Δ[NO]/Δ[3] = 2.06 ± 0.05, 3.09 ± 0.06 and 3.56 ± 0.20, respectively. The rate constant of NO release by complexes 1, 2, 3 under UV were determined in THF as 2.0 × 10 –4 s−1, 3.0 × 10 –4 s−1 and 6.0 × 10 –4 s−1. In addition, complexs 1, 2, and 3 released NO under blue light. All complexes cleaved DNA under UV irradiation.
author2 邱秀貞
author_facet 邱秀貞
林俊源
author 林俊源
spellingShingle 林俊源
Synthesis of Photochemical and Fluorescent NO-Releasing Molecule-RREs(Roussin’s Red Esters) Conjugating with Coumarin 343 as a Chromophore
author_sort 林俊源
title Synthesis of Photochemical and Fluorescent NO-Releasing Molecule-RREs(Roussin’s Red Esters) Conjugating with Coumarin 343 as a Chromophore
title_short Synthesis of Photochemical and Fluorescent NO-Releasing Molecule-RREs(Roussin’s Red Esters) Conjugating with Coumarin 343 as a Chromophore
title_full Synthesis of Photochemical and Fluorescent NO-Releasing Molecule-RREs(Roussin’s Red Esters) Conjugating with Coumarin 343 as a Chromophore
title_fullStr Synthesis of Photochemical and Fluorescent NO-Releasing Molecule-RREs(Roussin’s Red Esters) Conjugating with Coumarin 343 as a Chromophore
title_full_unstemmed Synthesis of Photochemical and Fluorescent NO-Releasing Molecule-RREs(Roussin’s Red Esters) Conjugating with Coumarin 343 as a Chromophore
title_sort synthesis of photochemical and fluorescent no-releasing molecule-rres(roussin’s red esters) conjugating with coumarin 343 as a chromophore
url http://ndltd.ncl.edu.tw/handle/92764370831597339921
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AT línjùnyuán héchéngjùyǒuyīyǎnghuàdànshìfàngnénglìjíyíngguāngxìngzhìcoumarin343zhīliúxīnsuānwèipèiwèijīzhīroussinsredesters
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