Asymmetric Total Synthesis of (-)-Pericosine A and Synthetic Studies toward (-)-Pericosine C
碩士 === 國立中興大學 === 化學系所 === 102 === This thesis we described the asymmetric synthesis of (-)-Pericosine A and C. Starting from commercial available C2-symmetrical L-tartaric acid, the target molecules could be accomplished within a short path. Critical to the fulfillment of this work was 1,4-conjugat...
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| Format: | Others |
| Language: | en_US |
| Published: |
2014
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| Online Access: | http://ndltd.ncl.edu.tw/handle/61628614740614704838 |
| Summary: | 碩士 === 國立中興大學 === 化學系所 === 102 === This thesis we described the asymmetric synthesis of (-)-Pericosine A and C. Starting from commercial available C2-symmetrical L-tartaric acid, the target molecules could be accomplished within a short path. Critical to the fulfillment of this work was 1,4-conjugate addition of cyanide reaction and the utilization of alcoholysis to the transformation from cyano moiety to carboxylic ester.
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