The paramagnetic NMR study of saddled metalloporphyrins- 1. Characterization of Saddled Nickel(III) Porphyrin Cation Radical :The NMR Explicative Model for Ferromagnetically Coupled Metalloporphyrin Radical. 2. Saddle-shaped six-coordinate iron(III) porphyrin complex with unusual intermediate-spin electronic structure
博士 === 國立中興大學 === 化學系所 === 102 === The two-electron oxidized NiII(OETPP)( 2,3,7,8,12,13,17,18-Octaethyl-5,10,15,20-tetraphenylporphyrin), which had merely been generated by eletrooxidation, is first chemically synthesized by addition of one equiv. of Br2 in benzene solution. The detailed magnetic pr...
| Main Authors: | , |
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| Format: | Others |
| Language: | zh-TW |
| Published: |
2014
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| Online Access: | http://ndltd.ncl.edu.tw/handle/81564703375984847254 |