Synthesis and characterization of metal complexes: 2-aza-2-[p-(isopropyl)benzyl]-5,10,15,20-tetraphenyl-21-carbaporphyrin: M(2-NCH2-p-C6H4-isoC3H7NCTPP) (M = Ni2+, Pd2+, Pt2+) and Chloro(2-aza-2-[p-(isopropyl)benzyl]-5,10,15,20-tetraphenyl-21- p-xylyl-21-carbaporphyrinato-N,N′,N′′) cobalt(II): Co(2-NCH2-p-C6H4-isoC3H7-21-CH2-p-C6H4CH3-NCTPP)Cl

Synthesis and characterization of metal complexes: 2-aza-2-[p-(isopropyl)benzyl]-5,10,15,20-tetraphenyl-21-carbaporphyrin: M(2-NCH2-p-C6H4-isoC3H7NCTPP) (M = Ni2+, Pd2+, Pt2+) and Chloro(2-aza-2-[p-(isopropyl)benzyl]-5,10,15,20-tetraphenyl-21- p-xylyl-21-carbaporphyrinato-N,N′,N′′) cobalt(II): Co(2-NCH2-p-C6H4-isoC3H7-21-CH2-p-C6H4CH3-NCTPP)Cl

碩士 === 國立中興大學 === 化學系所 === 102 === We use isopropyl benzyl bromide as alkylation reagent to react with N-confused porphyrin (NCP) to afford 2-aza-2-[p-(isopropyl)benzyl]-5,10,15,20-tetraphenyl-21-carbaporphyrin [2-NCH2-p-C6H4-isoC3H7NCTPPH; 2]. Then we use Ni(OAc)2∙4H2O, PdCl2, PtCl2 and CoCl2∙6H2O...

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Bibliographic Details
Main Authors: Chun-Chia Chiu, 邱俊嘉
Other Authors: Jyh-Horung Chen
Format: Others
Language:zh-TW
Published: 2014
Online Access:http://ndltd.ncl.edu.tw/handle/78794580984931997451

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http://ndltd.ncl.edu.tw/handle/78794580984931997451

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