Metal complexes of 2-aza-2-[p-(trifluoromethyl)benzyl]-5, 10, 15, 20-tetraphenyl-21-carbaporphyrin: M(2-NCH2-p-C6H4CF3NCTPP) (M=Ni2+, Pd2+, Pt2+) and 2-aza-2- [p-(trifluoromethyl)benzyl]-5, 10, 15, 20-tetraphenyl-21-carbaporphyrinato-N, N’, N’’-O)copper(II)： Cu(2-NCH2-p-C6H4CF3NCTPPO)
碩士 === 國立中興大學 === 化學系所 === 101 === We use p-(trifluoromethyl)benzyl bromide to proceed N-alkylation with N-confused prophyrin that synthesis 2-aza-2-[ p-(trifluoromethyl)benzyl]-5,10,15,20-tetraphenyl N-confused prophyin,we called as 2-NCH2-p-C6H4CF3NCTPPH(2). Secondly ,we use Ni ,Pd ,Pt and Cu as m...
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| Format: | Others |
| Language: | zh-TW |
| Published: |
2013
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| Online Access: | http://ndltd.ncl.edu.tw/handle/cjuaj3 |
| Summary: | 碩士 === 國立中興大學 === 化學系所 === 101 === We use p-(trifluoromethyl)benzyl bromide to proceed N-alkylation with N-confused prophyrin that synthesis 2-aza-2-[ p-(trifluoromethyl)benzyl]-5,10,15,20-tetraphenyl N-confused prophyin,we called as 2-NCH2-p-C6H4CF3NCTPPH(2).
Secondly ,we use Ni ,Pd ,Pt and Cu as metal reagent to get four complexes: Ni(2-NCH2-p-C6H4CF3NCTPP)(3)；Pd(2-NCH2-p-C6H4CF3NCTPP)(4)；Pt(2-NCH2-p-C6H4CF3NCTPP)(5) and Cu(2-NCH2-p-C6H4CF3NCTPP O)(6).
Then we use X-ray Single-Crystal Diffractometer ,NMR spectroscopy and EPR spectroscopy ,etc. ,to determine the crystal structure and to analyze the molecular characteristics.
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