| Summary: | 碩士 === 國防大學理工學院 === 化學工程碩士班 === 101 === National defense is the basis of national security and national benefits, and the explosives is one of the necessary elements to construct national combat power. Based on security, environmental protection and economy, how to deal with the energetic materials and effectively utilize the energy becomes the important direction for research and development. This study focus on the standpoints of recovery expired TNT and RDX, and the preparation of derived fuels with the energy released. Generally, it is thought that heat could be generated by the friction during the preparation of derived fuel by dry-pressing method. However, the explosives are sensitive and flammable. Except for using dry-pressing method, binders were also added to shape the derived fuels from wastes, and the samples were characterized by calorimetry, combustion and vacuum stability tests. The results show that the derived fuels made from the combination of explosives and wastes possess high combustion values and low air pollution, and they pass the vacuum stability tests. The combustion of derived fuels made by blending TNT with wood flour could reach 27095 J/g, which is approximately 85% of coal. It is expected that the as-formed derived fuels could be applied for industry.
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