Iron Trichloride-Promoted Construction of Spiro[4.6]undecan-8-ones

Iron Trichloride-Promoted Construction of Spiro[4.6]undecan-8-ones

碩士 === 國立臺灣師範大學 === 化學系 === 100 === 　　Construction of spiro[4.6]undecan-8-ones via iron(III) chloride-promoted tandem ring expansion/cyclization/chlorination of arylalkynyl-tethered bicyclo[4.1.0]heptan-2-ones was demonstrated. 　　Treatment of arylalkynyl-tethered bicyclo[4.1.0]heptan-2-ones with 1.5...

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Main Authors: Wei-Hang Chiu, 邱緯航
Other Authors: Ming-Chang P. Yeh
Format: Others
Language:zh-TW
Published: 2011
Online Access:http://ndltd.ncl.edu.tw/handle/99519317633751957257
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spelling ndltd-TW-100NTNU50651132016-03-28T04:20:21Z http://ndltd.ncl.edu.tw/handle/99519317633751957257 Iron Trichloride-Promoted Construction of Spiro[4.6]undecan-8-ones 三氯化鐵輔佐螺旋[4.6]十一-8-酮架構的合成 Wei-Hang Chiu 邱緯航 碩士 國立臺灣師範大學 化學系 100 　　Construction of spiro[4.6]undecan-8-ones via iron(III) chloride-promoted tandem ring expansion/cyclization/chlorination of arylalkynyl-tethered bicyclo[4.1.0]heptan-2-ones was demonstrated. 　　Treatment of arylalkynyl-tethered bicyclo[4.1.0]heptan-2-ones with 1.5 equivalents of iron(III) chloride in 1,2-dibromoethane at 50 ℃ afforded spiro[4.6]undecan-8-ones in 24-62 % yield. Structure elucidation of the (E)-form products was achieved by X-ray crystallography. Ming-Chang P. Yeh 葉名倉 2011 學位論文 ; thesis 111 zh-TW
collection NDLTD
language zh-TW
format Others
sources NDLTD
description 碩士 === 國立臺灣師範大學 === 化學系 === 100 === 　　Construction of spiro[4.6]undecan-8-ones via iron(III) chloride-promoted tandem ring expansion/cyclization/chlorination of arylalkynyl-tethered bicyclo[4.1.0]heptan-2-ones was demonstrated. 　　Treatment of arylalkynyl-tethered bicyclo[4.1.0]heptan-2-ones with 1.5 equivalents of iron(III) chloride in 1,2-dibromoethane at 50 ℃ afforded spiro[4.6]undecan-8-ones in 24-62 % yield. Structure elucidation of the (E)-form products was achieved by X-ray crystallography.
author2 Ming-Chang P. Yeh
author_facet Ming-Chang P. Yeh
Wei-Hang Chiu
邱緯航
author Wei-Hang Chiu
邱緯航
spellingShingle Wei-Hang Chiu
邱緯航
Iron Trichloride-Promoted Construction of Spiro[4.6]undecan-8-ones
author_sort Wei-Hang Chiu
title Iron Trichloride-Promoted Construction of Spiro[4.6]undecan-8-ones
title_short Iron Trichloride-Promoted Construction of Spiro[4.6]undecan-8-ones
title_full Iron Trichloride-Promoted Construction of Spiro[4.6]undecan-8-ones
title_fullStr Iron Trichloride-Promoted Construction of Spiro[4.6]undecan-8-ones
title_full_unstemmed Iron Trichloride-Promoted Construction of Spiro[4.6]undecan-8-ones
title_sort iron trichloride-promoted construction of spiro[4.6]undecan-8-ones
publishDate 2011
url http://ndltd.ncl.edu.tw/handle/99519317633751957257
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AT qiūwěiháng sānlǜhuàtiěfǔzuǒluóxuán46shíyī8tóngjiàgòudehéchéng
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