Electrochemically Induced Hydrogen Bonding of p-Phenylenediamines and Oligoarylamines

• Main Authors: PEI YU HSU, 徐珮瑜
• Other Authors: Yuhlong Oliver Su
• Format: Others
• Language: zh-TW
• Published: 2012
• Online Access: http://ndltd.ncl.edu.tw/handle/60887360731260584128

碩士 === 國立暨南國際大學 === 應用化學系 === 100 === This thesis involves two topics. The first topic has been concerned with the electrochemically induced hydrogen bonding of interaction between p-phenylenediamine derivatives and pyridines with different pKa. In experiment, there are three patterns including the first and second oxidation wave shifted in redox potential, two resolved electrochemical waves, then one shifted wave, and deprotonation. The second topic has been on the electrochemically interaction between the oxidized of oligoarylamines and various azo compounds. In cyclic voltammetry, the first oxidation wave remained unchanged while the second wave shfits in redox potential in the presence of a receptor. Spectroelectrochemistry has been also revealed the interaction by way of the intensity of different receptor.