Bond characterization of metal squarate complexes
碩士 === 明新科技大學 === 化學工程與材料科技研究所 === 100 === New coordinated polymers are composed of transition metal and 3,4- dihydroxy -3-cyclobutene-1,2-dione mixture ligand, The thesis report two metal complexes synthesized by Natural precipitation, The crystal structures of these two complexes were determined b...
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| Format: | Others |
| Language: | zh-TW |
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2011
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| Online Access: | http://ndltd.ncl.edu.tw/handle/37190776216071334935 |
| Summary: | 碩士 === 明新科技大學 === 化學工程與材料科技研究所 === 100 === New coordinated polymers are composed of transition metal and 3,4- dihydroxy -3-cyclobutene-1,2-dione mixture ligand, The thesis report two metal complexes synthesized by Natural precipitation, The crystal structures of these two complexes were determined by single crystal X-ray diffraction technique. The asphericity in electron density distribution around the metal ion is also clearly illustrated in these compounds both in the deformation density and in Laplacian of the density by WinGX and WinXD, The chemical formula of these crystals are the following:
(3) Mn(HC4O4)2(H2O)4
(4) Fe(HC4O4)2(H2O)4
Further information regarding to these two metal complexes were reported in chapter 4.of this thesis
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