Study on the Synthesis and the Photochemistry of 5-aryl-4,4-dimethoxy-2-cyclohexeones

Study on the Synthesis and the Photochemistry of 5-aryl-4,4-dimethoxy-2-cyclohexeones

碩士 === 臺北市立教育大學 === 自然科學系碩士班 === 99 === This study on the synthesis of 5-aryl-4,4-dimethoxy-2-cyclohexeones that 4,4-dimethoxy-2,5-cyclohex-di-enones be chelated carbonyl group by Lewis acid, MAD [methyl aluminium bis(2,6-di-tert-butyl-4-methyl phenoxide)],and then executed 1,4-addition with prepare...

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Main Author: 張瓅心
Other Authors: 古建國 許智偉
Format: Others
Language:zh-TW
Published: 2010
Online Access:http://ndltd.ncl.edu.tw/handle/26605075301300238627
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spelling ndltd-TW-099TMTC51470042015-10-30T04:04:59Z http://ndltd.ncl.edu.tw/handle/26605075301300238627 Study on the Synthesis and the Photochemistry of 5-aryl-4,4-dimethoxy-2-cyclohexeones 4,4-二甲氧基-5-芳香基環己-2-烯酮類的合成與光化學研究 張瓅心 碩士 臺北市立教育大學 自然科學系碩士班 99 This study on the synthesis of 5-aryl-4,4-dimethoxy-2-cyclohexeones that 4,4-dimethoxy-2,5-cyclohex-di-enones be chelated carbonyl group by Lewis acid, MAD [methyl aluminium bis(2,6-di-tert-butyl-4-methyl phenoxide)],and then executed 1,4-addition with prepared aryl grignard reagent, prepare as 0.01 M in trifluoroacetic ethanol respectively and carry out photochemistry reaction using 350 nm wavelength light. The results show that aromatic group is toluene causing the main skeleton of product is cyclopentanone on the other hand that aromatic group is thiophene causing the main skeleton of product is cyclobutanone. 古建國 許智偉 2010 學位論文 ; thesis 81 zh-TW
collection NDLTD
language zh-TW
format Others
sources NDLTD
description 碩士 === 臺北市立教育大學 === 自然科學系碩士班 === 99 === This study on the synthesis of 5-aryl-4,4-dimethoxy-2-cyclohexeones that 4,4-dimethoxy-2,5-cyclohex-di-enones be chelated carbonyl group by Lewis acid, MAD [methyl aluminium bis(2,6-di-tert-butyl-4-methyl phenoxide)],and then executed 1,4-addition with prepared aryl grignard reagent, prepare as 0.01 M in trifluoroacetic ethanol respectively and carry out photochemistry reaction using 350 nm wavelength light. The results show that aromatic group is toluene causing the main skeleton of product is cyclopentanone on the other hand that aromatic group is thiophene causing the main skeleton of product is cyclobutanone.
author2 古建國 許智偉
author_facet 古建國 許智偉
張瓅心
author 張瓅心
spellingShingle 張瓅心
Study on the Synthesis and the Photochemistry of 5-aryl-4,4-dimethoxy-2-cyclohexeones
author_sort 張瓅心
title Study on the Synthesis and the Photochemistry of 5-aryl-4,4-dimethoxy-2-cyclohexeones
title_short Study on the Synthesis and the Photochemistry of 5-aryl-4,4-dimethoxy-2-cyclohexeones
title_full Study on the Synthesis and the Photochemistry of 5-aryl-4,4-dimethoxy-2-cyclohexeones
title_fullStr Study on the Synthesis and the Photochemistry of 5-aryl-4,4-dimethoxy-2-cyclohexeones
title_full_unstemmed Study on the Synthesis and the Photochemistry of 5-aryl-4,4-dimethoxy-2-cyclohexeones
title_sort study on the synthesis and the photochemistry of 5-aryl-4,4-dimethoxy-2-cyclohexeones
publishDate 2010
url http://ndltd.ncl.edu.tw/handle/26605075301300238627
work_keys_str_mv AT zhānglìxīn studyonthesynthesisandthephotochemistryof5aryl44dimethoxy2cyclohexeones
AT zhānglìxīn 44èrjiǎyǎngjī5fāngxiāngjīhuánjǐ2xītónglèidehéchéngyǔguānghuàxuéyánjiū
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