1.Pyrolytic Studies of Arylimines2.Synthetic Studies of Natural Products With 2-Phenylbenzofuran framework by the Flash Vacuum Pyrolysis3.Pyrolytic Studies of Furylmethyl benzoates、Benzothienylmethyl benzoates and N-Methylpyrrolylmethyl benzoates
博士 === 國立中山大學 === 化學系研究所 === 99 === The thesis is divided into three chapters Chapter 1、Flash vacuum pyrolysis of 2-chloro-N-arenylideneaniline gave quinolines by the intromolecular cyclization. And then, flash vacuum pyrolysis of 2-methoxy-N-arenylideneaniline gave the benzothiazole products by the...
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| Format: | Others |
| Language: | zh-TW |
| Published: |
2011
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| Online Access: | http://ndltd.ncl.edu.tw/handle/72844515137645579097 |
| Summary: | 博士 === 國立中山大學 === 化學系研究所 === 99 === The thesis is divided into three chapters
Chapter 1、Flash vacuum pyrolysis of 2-chloro-N-arenylideneaniline gave quinolines by the intromolecular cyclization. And then, flash vacuum pyrolysis of 2-methoxy-N-arenylideneaniline gave the benzothiazole products by the bond cleavage and the radical reaction.
Chapter 2、Flash vacuum pyrolysis of 32 gave Stemofuran C. And then, flash vacuum pyrolysis of 33 gave 31 which belonging to the former compound of E6 reported on the paper. We also found that we also could get 2-phenylbenzofuran by flash vacuum pyrolysis of 44.
Chapter 3、Flash vacuum pyrolysis of furylmethyl benzoates、benzo-
thienylmethyl benzoates and N-methylpyrrolylmethyl benzoates gave the corresponding products by the interconversion between vinylcarbene and cyclopropene.
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