The study of phenyl azides reaction with electron-withdrawing group alkenes

• Main Authors: chia-hao Lou, 樓家豪
• Other Authors: chia-hsi Yang
• Format: Others
• Language: zh-TW
• Published: 2011
• Online Access: http://ndltd.ncl.edu.tw/handle/92384838214977891532

碩士 === 中原大學 === 化學研究所 === 99 === This study is the use of phenyl azide (for example: benzyl azide, chlorophenyl azide) with the electron-withdrawing alkenes (for example: methyl methacrylate, acrylonitrile) reaction. To investigate the reaction under high temperature condition between the previous results at room temperature and under high pressure at room temperature compared the results of what these differences. The experiment features a fast and simple preparation aziridine, let aniline turn into azidobenzene,and then reaction with the electron-withdrawing alkenes under 100 degree. The products are aziridine and triazole . the triazole turn into aziridine as faster as temperature increase. most patients do not need to experiment in the use of solvents as long as under high temperature conditions can be completed.