Synthesis, Structures, Magnetic Properties, and Catecholase-like Activities of Copper(II) Complexes

• Main Authors: Ruei-Yu Rao, 饒瑞峪
• Other Authors: Ho-Hsiang Wei
• Format: Others
• Language: zh-TW
• Published: 2010
• Online Access: http://ndltd.ncl.edu.tw/handle/88397450388572301473

碩士 === 淡江大學 === 化學學系碩士班 === 98 === The present paper discussion binuclear copper(II) complexs containing chemical constitution, magnetic behavior and relations of The reactive activies of catecholase-like. The content divides into two parts. Part I: binuclear copper (II) complexs synthesis and the magnetic behavior. Part II: The reactive activies of catecholase-like. (1)[Cu2(L1)-(μ-O)]．3H2O (2)[(CuL2)3-(μ3-OH)](ClO4)2．H2O (3)[Cu(L3)(CTZ)]2 (4)[Cu2(L4)4(K)]．2H2O L1: 2-(2-Hydroxyphenyl)-1,3-bis[2-(2-aminoethyl)imidazolidin-2-yl)phenoxy)acetic acid]imidazolidine L2: (Z)-4-(2-(ethylamino)ethylamino)pent-3-en-2-one L3: 2-((E)-(2-(dimethylamino)ethylimino)methyl)phenol L4: 2-((E)-(2-(dimethylamino)ethylimino)methyl)-6-methoxyphenol copper (II) complexs thing its nature by the single-crystal X-ray diffraction , the infrared spectra, and the element analyzer to understand that between the Cu-Cu coordinate spatial structure and the magnetic behavior''s relatedness, and observes its specific absorption in the UV-Vis spectra, discusses between its chemical constitution and Cu-Cu is away from to the catecholase catalytic activity influence.