| Summary: | 碩士 === 淡江大學 === 化學學系碩士班 === 98 === The present paper discussion binuclear copper(II) complexs containing chemical constitution, magnetic behavior and relations of The reactive activies of catecholase-like. The content divides into two parts.
Part I: binuclear copper (II) complexs synthesis and the magnetic behavior.
Part II: The reactive activies of catecholase-like.
(1)[Cu2(L1)-(μ-O)]．3H2O
(2)[(CuL2)3-(μ3-OH)](ClO4)2．H2O
(3)[Cu(L3)(CTZ)]2
(4)[Cu2(L4)4(K)]．2H2O
L1: 2-(2-Hydroxyphenyl)-1,3-bis[2-(2-aminoethyl)imidazolidin-2-yl)phenoxy)acetic acid]imidazolidine
L2: (Z)-4-(2-(ethylamino)ethylamino)pent-3-en-2-one
L3: 2-((E)-(2-(dimethylamino)ethylimino)methyl)phenol
L4: 2-((E)-(2-(dimethylamino)ethylimino)methyl)-6-methoxyphenol
copper (II) complexs thing its nature by the single-crystal X-ray diffraction , the infrared spectra, and the element analyzer to understand that between the Cu-Cu coordinate spatial structure and the magnetic behavior''s relatedness, and observes its specific absorption in the UV-Vis spectra, discusses between its chemical constitution and Cu-Cu is away from to the catecholase catalytic activity influence.
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